5,10,15,20-四苯基-21H,23H-卟吩钴(II)合成路线 （共 32 条）
反应条件
sodium acetate; potassium carbonate in N,N-dimethyl-formamide; chlorobenzene T=150°C;
参考文献
Polyhedron, , vol. 58, p. 2 - 6
反应条件
in N,N-dimethyl-formamide reflux for 1 h;
参考文献
Organometallics, , vol. 17, # 12 p. 2651 - 2655
反应条件
in N,N-dimethyl-formamide T=110°C; 1 h; Inert atmosphere;
参考文献
Macromolecules, , vol. 45, # 17 p. 6840 - 6849,10
反应条件
sodium carbonate in water T=349.84°C; 1 h; AutoclaveInert atmosphere;
参考文献
Chemistry Letters, , vol. 40, # 12 p. 1414 - 1416
反应条件
1-((trimethylsilyl)oxy)-1,3-cyclohexadiene in methanol pptn. on stirring (50 min); filtering, washing (MeOH);
参考文献
Organometallics, , vol. 16, # 16 p. 3679 - 3683
反应条件
Me3SiSiMe3; MeLi in tetrahydrofuran; N,N,N',N',N'',N''-hexamethylphosphoric triamide -78°C; elem. anal.;
参考文献
Chemical Communications, , # 2 p. 173 - 174
反应条件
hexamethyl-silane; methyllithium in tetrahydrofuran; N,N,N',N',N'',N''-hexamethylphosphoric triamide; diethyl ether N2-atmosphere; addn. of MeLi (ether) to soln. of disilane (HMPA) at 0°C, stirring for 15 min, addn. of THF, cooling (-78°C), addn.of soln. of Co-complex (THF), warming to 0°C for 1 h; pouring into pentane, washing (H2O), drying (MgSO4), evapn., chromy. (SiO2, CH2Cl2, 5percent MeOH in CH2Cl2), evapn., recrystn. (CH2Cl2:hexane); elem.anal.;
参考文献
Organometallics, , vol. 17, # 12 p. 2651 - 2655
反应条件
in N,N-dimethyl-formamide mixing 20percent molar excess of Co-compd. with free porphyrin base (refluxingin DMF under Ar for 30 min); according to: A. D. Adler, F. R. Longo, F. Kampas, J. Kim, J. Inorg. Nucl. Chem. 32 (1970) 2443; chromatography on silica gel (eluent dichloromethane), crystn. from dichloromethane-cyclohexane;
参考文献
Chemical Physics Letters, , vol. 293, # 1-2 p. 1 - 8
参考文献
Chemical Communications, , # 2 p. 173 - 174
反应条件
in pyridine refluxing porphyrin deriv. with cobalt compd. in pyridine;
参考文献
Angewandte Chemie - International Edition, , vol. 45, # 9 p. 1420 - 1422
