反应条件
sodium tetrahydroborate; (Z)-9-octadecenoic acid; N,N-distearyl-N,N-dimethylammonium bromide in toluene High Pressure; under N2; Cu salt and ((C18H37)2NMe2)Br added in toluene; stirred; heated to boiling; aq. NaBH4 added; C12H25SH added; stirred (room temp., 0.5-2 h); EtOH added; centrifuged; dispersed in toluene; oleic acid added; heated in autoclave (150-200°C); ppt. washed with EtOH; sepd. by centrifugation; detd. by X-ray diffraction, electron microscopy; Cu2S nanorods and nanodisks obtained;
参考文献
Shen, Shuling; Zhuang, Jing; Xu, Xiangxing; Nisar, Amjad; Hu, Shi; Wang, Xun
Inorganic Chemistry, 2009 , vol. 48, # 12 p. 5117 - 5128
