(三苯基膦)氯化金(I)合成路线 （共 181 条）
反应条件
1: acetone
2: acetone
3: NaH / dichloromethane
View Scheme
参考文献
Vicente, Jose; Chicote, Maria-Teresa; Huertas, Sonia; Ramirez De Arellano, M. Carmen; Jones, Peter G.
European Journal of Inorganic Chemistry, 1998 , # 4 p. 511 - 516
反应条件
in dichloromethane-d2
T=-90°C; Inert atmosphereGloveboxSealed tube;
参考文献
Joost, Maximilian; Gualco, Pauline; Coppel, Yannick; Miqueu, Karinne; Kefalidis, Christos E.; Maron, Laurent; Amgoune, Abderrahmane; Bourissou, Didier
Angewandte Chemie - International Edition, 2014 , vol. 53, # 3 p. 747 - 751
Angew. Chem., 2013 , vol. 126, # 3 p. 766 - 770,5
反应条件
in tetrahydrofuran
byproducts: Au, Me3Si-C*C-C*C-SiMe3; equimolar amts., 25°C;
参考文献
Koehler, Katrin; Silverio, Sandro J.; Hyla-Kryspin, Isabella; Gleiter, Rolf; Zsolnai, Laszlo; Driess, Alexander; Huttner, Gottfried; Lang, Heinrich
Organometallics, 1997 , vol. 16, # 23 p. 4970 - 4979
反应条件
1: not given
2: acetonitrile
View Scheme
参考文献
McAuliffe, Charles A.; Parish, R. V. (Dick); Randall, P. David
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1979 , p. 1730 - 1735
反应条件
in not given
byproducts: PPh3;
参考文献
McAuliffe, Charles A.; Parish, R. V. (Dick); Randall, P. David
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1979 , p. 1730 - 1735
反应条件
in tetrahydrofuran
(Ar); addn. of THF soln. of vinylmetalloderiv. to THF soln. of gold compd. at -20°C, stirring for 20 min, warming to room temp., stirringfor 1 h; Y. Shi, S.D. Ramgren and S.A. Blum, Organometallics, 2009, 28, 1275; evapn. in vac., addn. of benzene, filtration through celite, evapn. in vac., washing with pentane, drying, extn. (benzene), filtration, washing with pentane, drying in high vac., NMR and MS;
参考文献
Pena-Lopez, Miguel; Ayan-Varela, Miguel; Sarandeses, Luis A.; Sestelo, Jose Perez
Organic and Biomolecular Chemistry, 2012 , vol. 10, # 8 p. 1686 - 1694
反应条件
in tetrahydrofuran; diethyl ether
under Ar, Schlenk techniques; suspn. of Au compd. in Et2O treated at -78°C with soln. of Mg compd. in THF (0.929:1.000 molar ratio); warmed to room temp. in 4 h, exposed to air for 10 min, filtered (MgSO4), evapd. (vac.), elem. anal.;
参考文献
Mohr, Fabian; Falvello, Larry R.; Laguna, Mariano
European Journal of Inorganic Chemistry, 2006 , # 4 p. 833 - 838
反应条件
in tetrahydrofuran
T=25°C; Inert atmosphere; Equilibrium constant;
参考文献
Delpozo, Juan; Carrasco, Desiree; Perez-Temprano, Monica H.; Garcia-Melchor, Max; Alvarez, Rosana; Casares, Juan A.; Espinet, Pablo
Angewandte Chemie - International Edition, 2013 , vol. 52, # 8 p. 2189 - 2193
Angew. Chem., 2013 , vol. 125, # 8 p. 2245 - 2249
反应条件
in tetrahydrofuran
under dry N2;
参考文献
Schmidbaur, Hubert; Inoguchi, Yoshio
Chemische Berichte, 1980 , vol. 113, # 5 p. 1646 - 1653
反应条件
in tetrahydrofuran
soln. of Mg compd. in Schlenk tube was heated at 50°C for 15 min;soln. of Au complex in THF was added dropwise over 1 min; heated at 50. degree.C for 15 min; cooled (ice bath, 5 min); quenched (ice); dild. (Et2O); washed (H2O); org. layer septd.; dried (K2HCO3); filtered; concd. (vac.); chromd. (alumina, THF); concd. (vac.); dissolved (C6H6); layered (pentane); recrystd. (4°C, 3 d); filtered; washed;
参考文献
Roth, Katrina E.; Blum, Suzanne A.
Organometallics, 2010 , vol. 29, # 7 p. 1712 - 1716
