双(三苯基膦)氯化镍(II)合成路线 （共 36 条）
反应条件
in water; acetic acid washing with acetic acid, drying in vac. over concd. H2SO4 or KOH;
参考文献
Journal of the Chemical Society, , p. 719 - 724
Ni: MVol.C2, 8.18.1, page 1041 - 1052
反应条件
in ethanol heating with reflux;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 27, p. 501 - 505
反应条件
in benzene under Ar atm. using Schlenk techniques; a flask was charged with Ni complex in benzene; vinyl chloride was condensed into the tube at -78°C under vac.; soln. stirred for 4 ds at 50°C; cooled to room temp.; volatiles removed (vac.); filtered; filtrate was left to stand at 25°C for 24 h; red brown crystals pptd. and sepd. by filtration; filtrate heated to 50°C for 4 ds; filtered; condensed under vac.; cooled to -36°C; dark red crystals;
参考文献
Journal of the American Chemical Society, , vol. 125, # 14 p. 4350 - 4361
反应条件
1: methanol 2: water; acetic acid View Scheme
参考文献
Ni: MVol.C2, 8.18.1, page 1041 - 1052
反应条件
1: Br2 2: methanol 3: water; acetic acid View Scheme
参考文献
Ni: MVol.C2, 8.18.1, page 1041 - 1052
反应条件
hydrogenchloride in methanol; water in aq. methanolic soln. at 150°C during 8 h under Ar;;
参考文献
Inorganica Chimica Acta, , vol. 96, p. 179 - 186
参考文献
Liebigs Annalen der Chemie, , vol. 560, p. 104 - 116
反应条件
P(C6H5)3 in toluene N2-atmosphere; equimolar amts., 220-240 K; product mixt. not sepd., detd. by (31)P-NMR spectroscopy;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , # 21 p. 3075 - 3084
反应条件
in acetone N2-atmosphere; addn. of stoich. amt. of metal chloride to thiocarboxamido-complex (pptn.);
参考文献
Inorganica Chimica Acta, , vol. 51, p. 263 - 272
参考文献
Bulletin of the Chemical Society of Japan, , vol. 46, p. 686
