双(三苯基膦)氯化镍(II)合成路线 （共 36 条）
参考文献
Bulletin of the Chemical Society of Japan, , vol. 53, # 1 p. 139 - 145
参考文献
Ni: Org.Verb.2, 1.4.1.4, page 78 - 83
反应条件
carbon monoxide in tetrahydrofuran byproducts: NaCl; addn. of n-C4H9ONa to suspn. of Ni compd., CO (40 bar), room temp., 20h, hydrolysis with H2SO4, sepn. of organic phase, dried; yield of organic products detected by chromy.;
参考文献
Journal of Organometallic Chemistry, , vol. 254, # 2 p. 267 - 272
反应条件
carbon monoxide in tetrahydrofuran byproducts: ZnCl2; stirring Zn-dust with Ni-complex under CO (room temp., 1 h); filtration, pptn. on addn. of 50percent aq. EtOH, washing (aq. EtOH), drying (vac.); elem. anal.;
参考文献
Inorganica Chimica Acta, , vol. 37, p. L455 - L456
反应条件
sodium thiomethoxide in ethanol byproducts: CH3SSCH3, NaCl; react. of suspension of Ni(P(C6H5)3)2Cl2 in C2H5OH;; pptn., recrystn. from benzene/ethanol;;
参考文献
Chem. Letters, , p. 831 - 832
反应条件
water in tetrahydrofuran byproducts: W2(CO)6(C5H5)2, Ni(W(CO)3(C5H5))2(P(C6H5)3)2; educts reacted in THF at ambient temp. for 2-10 min, water added; filtered, washed with acetone, recrystd. from CH2Cl2-hexane; elem. anal.;
参考文献
Organometallics, , vol. 4, p. 1138 - 1140
反应条件
water in tetrahydrofuran byproducts: Mo2(CO)6(C5H5)2; educts reacted in THF at ambient temp. for 2-10 min, water added; filtered, washed with acetone, recrystd. from CH2Cl2-hexane; elem. anal.;
参考文献
Organometallics, , vol. 4, p. 1138 - 1140
反应条件
in butan-1-ol at 180°C and 5 atm;; pptn.;;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 27, p. 516 - 520
反应条件
in tetrahydrofuran a soln. of Na-salt in THF was added to Ni-complex, the mixt. stirred at room temp. for 10 min, H2O was added (over 1-2 min), solid was sepd. by filtration; solid was washed with H2O, then acetone, crystd. from CH2Cl2-hexane at -20°C, washed with hexane, dried in vac.; to the filtrate contg. W2(CO)6(Cp)2 (IR) hexane was added, on standing for 14 d crystn. of W-Cl and Ni-complex; elem. anal.;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 2741 - 2750
反应条件
in further solvent(s) prepn. from Ni(P(C6H5)3)2Cl2 and Ni(CO)4 in Cl(CH2)2CN at 45-55°C, addn. of C2H5OH;; pptn.;;
