water in water
byproducts: O; Electrolysis; side reaction of electrolysis of NaCl soln. without diaphragm, the more formation of chlorate the less concn. of chloride;;
参考文献
Foerster, F.
Z. Anorg. Chem., 1899 , vol. 22, p. 1 - 1
Roberto, U.; Roncali, F.
Ind. Chim. (Rome), 1904 , vol. 6, p. 93
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Williams, H. G.
Chem. News J. Ind. Sci., 1913 , vol. 107, p. 109
White, J. F.; Taylor, M. C.; Vincent, G. P.
Industrial and Engineering Chemistry, 1942 , vol. 34, p. 782 - 792
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Gmelin Handbook: Cl: SVol.B2, 40, page 402 - 404
catalyst: Ir-compounds in water
Kinetics; spantaneous decompn. at pH = 9;;
参考文献
Ayres, G. H.; Booth, M. H.
Journal of the American Chemical Society, 1955 , vol. 77, p. 825 - 827
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Gmelin Handbook: Cl: SVol.B2, 32, page 384 - 386
NHCO3 or acetic acid or H3PO4 or H2SO4 in water
byproducts: HClO or chlorate, O2; formation of products depends on: concn. of hypochloride, temp. of soln., concn. of acid;;
sulfuric acid in not given
the use of an excess of H2SO4 generates Cl2;;
参考文献
Gay-Lussac
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1842 , vol. 14, p. 942 - 942
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Gmelin Handbook: Cl: MVol., 92, page 249 - 251
