(S)-(-)-1-苯基乙醇合成路线 （共 393 条）
反应条件
novozyme 435; zeolite beta Al-150 in toluene T=60°C;
参考文献
Chemistry - A European Journal, , vol. 13, # 2 p. 541 - 547
反应条件
1: 47 percent / 0.1M phosphate buffer, lipase, 1M NaOH / 10 h / 20 °C 2: 97 percent / K2CO3 / methanol / 1 h / Ambient temperature View Scheme
参考文献
Journal of the Chemical Society, Chemical Communications, , p. 598 - 600
反应条件
1: diethyl ether / 12 h / -60 - 20 °C 2: Na2S 3: 1.) Na; 2.) AcOH, NaOH / 1.) 0 deg C; 2.) THF, 20 deg C View Scheme
参考文献
Helvetica Chimica Acta, , vol. 64, # 7 p. 2485 - 2488
反应条件
1.1: sodium tetrahydroborate 2.1: potassium bromide / water / 0.17 h / 25 °C / |Resolution of racemate 2.2: 2 h / 25 °C View Scheme
参考文献
Applied Catalysis A: General, , vol. 458, p. 1 - 10
反应条件
1.1: potassium bromide / water / 0.17 h / 25 °C / |Resolution of racemate 1.2: 2 h / 25 °C 2.1: sodium tetrahydroborate 3.1: potassium bromide / water / 0.17 h / 25 °C / |Resolution of racemate 3.2: 2 h / 25 °C View Scheme
参考文献
Applied Catalysis A: General, , vol. 458, p. 1 - 10
反应条件
hydrogen cation in water Yield given;
参考文献
Chemische Berichte, , vol. 117, # 4 p. 1330 - 1354
反应条件
potassium tert-butylate; isopropyl alcohol; [RhCl(η2:η2-cycloocta-1,5-diene)]2; PhHN-C(S)-N(CH3)-CH(Ph)-CH(Ph)-N(CH3)-C(S)-NHPh 1.) 90 min; 2.) r.t., overnight, 82 deg C, 1 d; Yield given. Multistep reaction;
参考文献
Journal of Organometallic Chemistry, , vol. 567, # 1-2 p. 133 - 136
反应条件
Rh(1+)*BF4(1-); dihydrogen peroxide; (-)-bis(5-diphenylphosphono-tetrahydroindenyl)iron in toluene T=-50°C; Addition; oxidation; 12 h; 2.) H2O2, NaOH; Product distribution; Further Variations:CatalystsSolvents;
参考文献
Tetrahedron Letters, , vol. 40, # 27 p. 4977 - 4980
反应条件
roots of Apium graveolens L; var. rapaceum in phosphate buffer; acetone pH=6.2; 48 h; Title compound not separated from byproducts;
参考文献
Mczka, Wanda K; Mironowicz, Agnieszka
Tetrahedron Asymmetry, 2002 , vol. 13, # 21 p. 2299 - 2302
反应条件
1,8-diazabicyclo[5.4.0]undec-7-ene; phenol in toluene
参考文献
Synthesis, , # 8 p. 1306 - 1315
