二(三甲基甲硅烷基)乙炔合成路线 （共 218 条）
反应条件
2.) acid; tetrabutyl ammonium fluoride
1.) -78 deg C / 36 h, 0 deg C / 4 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Kuwajima, I.; Nakamura, E.; Hashimoto, K.
Tetrahedron, 1983 , vol. 39, # 6 p. 975 - 982
反应条件
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine in tetrahydrofuran
T=45°C; Inert atmosphereSchlenk technique;
参考文献
Lin, Yan; Jiang, Chuanyin; Hu, Fang; Yin, Jun; Yu, Guang-Ao; Liu, Sheng Hua
Dyes and Pigments, 2013 , vol. 99, # 3 p. 995 - 1003
反应条件
ethanolamine; dodecacarbonyltriiron
T=60°C; 28 h;
参考文献
Fuchikami, Takamasa; Ojima, Iwao
Tetrahedron Letters, 1984 , vol. 25, # 3 p. 303 - 306
反应条件
aluminium trichloride in dichloromethane
T=-10°C; 3 h;
参考文献
Chemin, Denis; Linstrumelle, Gerard
Tetrahedron, 1992 , vol. 48, # 10 p. 1943 - 1952
反应条件
methyllithium; lithium bromide
1.) THF, 20 deg C, 2 h, 2.) HMPA, r.t., overnight;
参考文献
Meyer, Christophe; Marek, Ilane; Courtemanche, Gilles; Normant, Jean-F.
Journal of Organic Chemistry, 1995 , vol. 60, # 4 p. 863 - 871
反应条件
1: AlCl3, aluminium chloride / dichloromethane / 0 °C / Inert atmosphere
2: carbon tetrabromide; triphenylphosphine / dichloromethane / Inert atmosphere
3: n-butyllithium / hexane / -78 - -20 °C / Inert atmosphere
View Scheme
参考文献
Graham, Erin R.; Tykwinski, Rik R.
Journal of Organic Chemistry, 2011 , vol. 76, # 16 p. 6574 - 6583
反应条件
byproducts: THF; from -196°C to 0°C, 6 h stirred at 0°C; volatiles destilled out at 0°C, chromatographed on silica-gel in CHCl3, vacuum sublimation at 78°C, vacuum fractional destillation at 70°C;
参考文献
Hosmane, Narayan S.; Sirmokadam, Narayan N.; Mollenhauser, Mark N.
Journal of Organometallic Chemistry, 1985 , vol. 279, p. 359 - 372
反应条件
15 days 23°C; fractionated through traps, elem. anal.;
参考文献
Hosmane, Narayan S.; Sirmokadam, Narayan N.; Mollenhauser, Mark N.
Journal of Organometallic Chemistry, 1985 , vol. 279, p. 359 - 372
参考文献
Baum, Kurt; Tzeng, Dongjaw
Journal of Organic Chemistry, 1985 , vol. 50, # 15 p. 2736 - 2739
反应条件
aluminium trichloride in dichloromethane
T=20°C; 3 h;
参考文献
Graham, Erin R.; Tykwinski, Rik R.
Journal of Organic Chemistry, 2011 , vol. 76, # 16 p. 6574 - 6583
