二(三甲基甲硅烷基)乙炔合成路线 （共 218 条）
反应条件
trimethylamine-N-oxide; dimethylsulfide borane complex; water
1.) THF, 0-5 deg C, 2 h; 2.) 25-55 deg C, 30 min; 3.) 5 sec;
参考文献
Miller, Joseph A.; Zweifel, George
Synthesis, 1981 , # 4 p. 288 - 289
反应条件
1: 75 percent / AlCl3 / CH2Cl2 / 12 h / Ambient temperature
2: 78 percent / i-Bu2AlH / toluene / 2 h / -20 °C
View Scheme
参考文献
Eisch, John J.; Behrooz, Mohammad; Dua, Suresh K.
Journal of Organometallic Chemistry, 1985 , vol. 285, p. 121 - 136
反应条件
1: AlCl3, aluminium chloride / dichloromethane / 0 °C / Inert atmosphere
2: carbon tetrabromide; triphenylphosphine / dichloromethane / Inert atmosphere
3: n-butyllithium / hexane / -78 - -20 °C / Inert atmosphere
View Scheme
参考文献
Graham, Erin R.; Tykwinski, Rik R.
Journal of Organic Chemistry, 2011 , vol. 76, # 16 p. 6574 - 6583
反应条件
1: With cyclopentadienylcobaltbis(ethene) in tetrahydrofuran
T=20°C; 1 h;
2: With tetrabutyl ammonium fluoride in tetrahydrofuran
T=20°C; 2 h;
3: With iron nitrate (III) in tetrahydrofuran; water
T=20°C; 0.0333333 h; Further stages.;
参考文献
Aubert, Corinne; Betschmann, Patrick; Eichberg, Michael J.; Gandon, Vincent; Heckrodt, Thilo J.; Lehmann, Juerg; Malacria, Max; Masjost, Birgit; Paredes, Elisa; Vollhardt, K. Peter C.; Whitener, Glenn D.
Chemistry - A European Journal, 2007 , vol. 13, # 26 p. 7443 - 7465
反应条件
η5-cyclopentadienyl dicarbonyl cobalt; cesium fluoride
1.) THF, reflux, irradiation, 2.) DMSO, 79-80 deg C, 3 d; Yield given. Multistep reaction;
参考文献
Grotjahn; Vollhardt
Synthesis, 1993 , # 6 p. 579 - 605
反应条件
aluminium trichloride
参考文献
Heiss, Christian; Phillips, Robert S.
Journal of the Chemical Society, Perkin Transactions 1, 2000 , # 16 p. 2821 - 2825
反应条件
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; water; 1,8-diazabicyclo[5.4.0]undec-7-ene in benzene
18 h; Inert atmosphereCooling with ice;
参考文献
Zhou, Feng; Han, Xiuling; Lu, Xiyan
Tetrahedron Letters, 2011 , vol. 52, # 36 p. 4681 - 4685
反应条件
1: tri-phenyl-antimony With [bis(acetoxy)iodo]benzene in dichloromethane
T=20°C; 7 h;
2: bis(trimethylsilyl)-acetylene With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; copper(l) iodide in acetonitrile
T=50°C; 5 h; Further stages.;
参考文献
Kang, Suk-Ku; Ryu, Hyung-Chul; Hong, Young-Taek
Journal of the Chemical Society. Perkin Transactions 1, 2001 , # 7 p. 736 - 739
