氯化三(三苯基膦)合铑(I)合成路线 （共 95 条）
反应条件
in benzene
T=80°C; 24 h; Heating; MechanismProduct distribution;
参考文献
Kampmeier, J. A.; Harris, S. H.; Wedegaertner, D. K.
Journal of Organic Chemistry, 1980 , vol. 45, # 2 p. 315 - 318
反应条件
in THF-d8 (tetrahydrofuran-d8)
byproducts: P(C6H5)3; addn. of soln. of catecholborane to soln. of Rh-complex and oct-1-ene (-78°C, NMR tube), warming (-40°C, (31)P-NMR monitoring), warming to 25°C; (11)B-NMR spectroscopy;
参考文献
Burgess, Kevin; Van Der Donk, Wilfred A.; Westcott, Stephen A.; Marder, Todd B.; Baker, R. Thomas; Calabrese, Joseph C.
Journal of the American Chemical Society, 1992 , vol. 114, # 24 p. 9350 - 9359
反应条件
in dichloromethane-d2
byproducts: H2, P(C6H5)3; dropwise addn. of soln. of catecholborane to soln. of Rh-complex; not isolated; (1)H-, (11)B- and (31)P-NMR spectroscopy; further products;
参考文献
Burgess, Kevin; Van Der Donk, Wilfred A.; Westcott, Stephen A.; Marder, Todd B.; Baker, R. Thomas; Calabrese, Joseph C.
Journal of the American Chemical Society, 1992 , vol. 114, # 24 p. 9350 - 9359
反应条件
in benzene
N2 atmosphere; refluxing (7 h); removal of benzene, dissoln. (CH2Cl2), pptn. on addn. of MeOH, filtn., washing (hexane), drying (air);
参考文献
Song, Linsheng; Arif, Atta M.; Stang, Peter J.
Organometallics, 1990 , vol. 9, p. 2792 - 2797
反应条件
hydrogen in ethanol
T=20°C;
参考文献
Gonzalez-Gomez, Jose C.; Medjahdi, Mohamed; Foubelo, Francisco; Yus, Miguel
Journal of Organic Chemistry, 2010 , vol. 75, # 18 p. 6308 - 6311
