氯化三(三苯基膦)合铑(I)合成路线 （共 95 条）
反应条件
in further solvent(s) argon-filled glovebox, 1 equiv. of RhCl(PPh3)3 was heated 2-12h at 130-140°C, other solvent; detd. spect.;
参考文献
Andrews, Mark A.
Organometallics, 1989 , vol. 8, p. 2703 - 2708
反应条件
in further solvent(s) argon-filled glovebox, durene, bibenzyl, 130°C, 23h; product detd. by GC and IR;
参考文献
Andrews, Mark A.
Organometallics, 1989 , vol. 8, p. 2703 - 2708
反应条件
1-hexene in 1,2-dichloro-ethane byproducts: styryltriphenyltriphosphonium chloride; evacuated and N2 added two times; dichloroethane addn.; evacuated untilboiled at room temp., and N2 added rapidly; cycle repeated; cooled to -78°C, tube sealed; heated 85°C 24 h; decane added; distd. the volatiles; residue recrysd. from dichloroethane;
参考文献
Kampmeier, J. A.; Harris, S. H.; Rodehorst, R. M.
Journal of the American Chemical Society, 1981 , vol. 103, # 6 p. 1478 - 1485
反应条件
carbon monoxide in chloroform
参考文献
Kampmeier, J. A.; Rodehorst, R. M.; Philip, J. B.
Journal of the American Chemical Society, 1981 , vol. 103, p. 1847 - 1849
反应条件
methyl acetylene in 1,2-dichloro-ethane byproducts: hexyne, 1-chloro-1-hexene, hexenyl phosphonium salts; evacuated and N2 added two times; dichloroethane and propyne addn.; evacuated until boiled at room temp., and N2 added rapidly; cycle repeated;cooled to -78°C, tube sealed; refluxed 2 h; decane added; distd. the volatiles; residue recrystd. from dichloroethane;
参考文献
Kampmeier, J. A.; Harris, S. H.; Rodehorst, R. M.
Journal of the American Chemical Society, 1981 , vol. 103, # 6 p. 1478 - 1485
反应条件
styryltriphenylphosphonium chloride in 1,2-dichloro-ethane byproducts: 1-propenyltriphenylphosphonium chloride, 1-choro-1-propene; evacuated and N2 added two times; dichloroethane addn.; evacuated until boiled at room temp., and N2 added rapidly; cycle repeated; cooled to -78°C, tube sealed; reflux 1 h; decane added; distd. volatiles; from residue recrystd. at -10°C;;
参考文献
Kampmeier, J. A.; Harris, S. H.; Rodehorst, R. M.
Journal of the American Chemical Society, 1981 , vol. 103, # 6 p. 1478 - 1485
反应条件
catalyst: HCl in further solvent(s) argon-filled glovebox, bibenzyl, 130°C, 30min.; product detd. by GC;
参考文献
Andrews, Mark A.
Organometallics, 1989 , vol. 8, p. 2703 - 2708
反应条件
in acetonitrile-D3 evacuated and N2 added two times; CD3CN addn.; evacuated until boiled at room temp., and N2 added rapidly; cycle repeated; cooled to -78°C, tube sealed; heated 85°C 4 d; decane added; distd.; the volatiles chromd.; residue recrystd.;
参考文献
Journal of the American Chemical Society, , vol. 103, # 6 p. 1478 - 1485
反应条件
in toluene byproducts: CO; 5 h, 111°C, excess p-methylbenzoyl chloride;
参考文献
Journal of the American Chemical Society, , vol. 103, p. 1847 - 1849
反应条件
in acetonitrile evacuated and N2 added two times; acetonitrile-acid chloride introduced; evacuated until the solvent boiled at room temp. then N2 added rapidly; cycles repeated; cooled to -75°C; sealed; in oil bath 85°C 24 h; decane added; styrene distd.; Rh comp. recrystd. from CH2Cl2; from filtrate chromd. styryl(PPh3)Cl;
参考文献
Journal of the American Chemical Society, , vol. 103, # 6 p. 1478 - 1485
