in water
Kinetics; byproducts: H(1+); kinetic measurements carried out in a standard 1 cm quartz cuvette equipped with a Teflon cap and a magnetic stirrer; acetic acid-acetate bufferused to maintain the pH; reaction carried out at various pH and concent rations of chlorite and tetrathionate; not isolated, detected by UV-VIS spectroscopy;
参考文献
Horvath, Attila K.
Journal of Physical Chemistry A, 2005 , vol. 109, # 23 p. 5124 - 5128
in water
equal vols. of Na2S2O3 aq. soln. (concn. of 100.0 μmol dm**-3) and H2O2 aq. soln. (concn. of 2.00 mmol dm**-3) mixed well; react. run at 25 °C and pH 6 for >5000 min; SO4(2-) determined by ion chromy.; S3O6(2-) and S4O6(2-) determined by HPLC with UV-visible detector;
参考文献
Sato, Keiichi; Furuya, Satoshi; Takenaka, Norimichi; Bandow, Hiroshi; Maeda, Yasuaki; Furukawa, Yoshinori
Bulletin of the Chemical Society of Japan, 2003 , vol. 76, # 6 p. 1139 - 1144
in water
Kinetics; byproducts: CH3COO; reacting sulfate radicals (produced by laser-flash photolysis of Na2S2O8) with CH3COO(1-) (8.5 - 63.0°C, pH 6.6 - 7.2); monitoring reaction by UV spectroscopy;
参考文献
Huie, Robert E.; Clifton, Carol L.
Journal of Physical Chemistry, 1990 , vol. 94, # 23 p. 8561 - 8567
in water
using oxygen-saturated solns.; addn. of sulfite soln. to soln. of copper(II) tetraglycine (containing Ni(II) as impurity) at pH = 7 and 25°C; monitoring by UV;
参考文献
Moreno, Ruben G. M.; Alipazaga, Maria V.; Medeiros, Marisa H. G.; Coichev, Nina
Dalton Transactions, 2005 , # 6 p. 1101 - 1107
→
反应条件
in melt
reaction by addition of SnCl2 to Na2SO3 in an eutectic LiCl-KCl melt;;
参考文献
Delarue, G.
Bulletin de la Societe Chimique de France, 1960 , p. 906 - 910
Full Text Show Details
Gmelin Handbook: Sn: MVol.C2, 9.3.2.2, page 7 - 8
