in diethyl ether; water (N2, protection from light); addn. of KCl to AgNO3 in H2O, addn. of PMePh2 in Et2O, vigorous stirring (24 h); recrystn. (CH2Cl2/EtOH); elem. anal.;
参考文献
Copley, Royston C. B.; Mingos, D. Michael P.
Journal of the Chemical Society - Dalton Transactions, 1996 , # 4 p. 491 - 500
in various solvent(s) T=135°C; other atomtransfer (S and Se) reactions; Rate constantEquilibrium constant;
参考文献
Baechler, Raymond D.; Stack, Mary; Stevenson, Karen; Vanvalkenburgh, Virginia
Phosphorus, Sulfur and Silicon and the Related Elements, 1990 , vol. 48, # 1-4 p. 49 - 52
chloroform in chloroform; acetone byproducts: CH2Cl2; under Ar, soln. of Fe complex in CHCl3 and acetone treated with PMePh2,stirred for 1 h; volatiles flash-distd. at room temp., residue washed with hexane, dried, identified by NMR, IR;
