(2,2-联吡啶)二氯钯(II)合成路线 （共 41 条）
反应条件
in dimethyl sulfoxide Kinetics; reaction of trans-(PdCl2((CH3)2SO)2) and 2,2'-bipyridine in (CH3)2SO at 25°C; reaction mechanism discussed;;
参考文献
Inorganica Chimica Acta, , vol. 215, p. 41 - 46
反应条件
in benzene on react. in soln. of benzene with dipyridine in benzene for a longer period of time at about 60 °C, forming of (Pd(C10H8N2)Cl2); on concg. of filtrate, forming of (Pd2(PBu3)2(C2H5S)2Cl2), from mother liquid, isolation of (Pd(PBu3)2Cl2);;
参考文献
Journal of the Chemical Society, , p. 1950 - 1950
Journal of the Chemical Society, , p. 1953 - 1953
反应条件
in chloroform-d1 byproducts: PPh(C6H4Cl-2)2; NMR tube was charged with Pd-complex and ligand in CDCl3, heated to 90°C for 1 h;
参考文献
Inorganica Chimica Acta, , vol. 342, p. 236 - 240
反应条件
in dimethyl sulfoxide suspn. of Pd complex (0.035 mmol), Pd(dba)2 (0.035 mmol), and 2,2'-bipyridine (0.035 mmol) in DMSO stirred at room temp. for 1 d; filtered through Celite, filtrate added to CH2Cl2/Et2O (1/1), ppt. sepd.by centrifugation, dried under vac.; mixt. not sepd.;
参考文献
European Journal of Inorganic Chemistry, , # 9 p. 1394 - 1402
反应条件
in 1,2-dichloro-ethane 100°C;
参考文献
Journal of General Chemistry USSR (English Translation), , vol. 59, p. 1620 - 1624
Zhurnal Obshchei Khimii, , vol. 59, p. 1818 - 1823
反应条件
in dichloromethane byproducts: 2,2-dimethylpent-3-enyl methyl sulphide; not deparayted, determined by n.m.r.;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , # 1 p. 137 - 144
反应条件
in ethanol EtOH soln. of 2,2-bipyridine added dropwise to EtOH soln. of Pd(MeCN)2Cl2 at 60°C; cooled to room temp. after ca 1 h; filtered; washed with EtOH; dried in vac.;
参考文献
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, , vol. 65, # 9 p. 1121 - 1127
反应条件
in dichloromethane N2-atmosphere; addn. of 1 equiv. Pd(NCPh)2Cl2 to butadiene complex (pptn.); filtration off of bipy-complex, evapn. (reduced pressure), washing (light petroleum), drying in air;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 178 - 183
反应条件
isothermal heating at 160°C; elem. anal.;
参考文献
Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), , vol. 23, p. 1032 - 1035
Zhurnal Neorganicheskoi Khimii, , vol. 23, p. 1877 - 1883
反应条件
in acetonitrile to suspn. PdCl2(dipy) in CH3CN was added piperidine (1:2), suspn. was allowed to react under stirring with CO (0.1 MPa) at room temp. for 3 h; filtered off, washed with CH3CN/CH3OH (10:1), and dried in vacuo; elem.anal.;
参考文献
Aresta, Michele; Giannoccaro, Potenzo; Tommasi, Immacolata; Dibenedetto, Angela; Lanfredi, Anna Maria Manotti; Ugozzoli, Franco
Organometallics, 2000 , vol. 19, # 19 p. 3879 - 3889
