3-苯基-2-丙炔-1-醇合成路线 （共 165 条）
反应条件
1.1: bromine; triphenylphosphine 2.1: 1,8-diazabicyclo[5.4.0]undec-7-ene / N,N-dimethyl-formamide / 20 °C 3.1: hydrazine hydrate / methanol; dichloromethane / 20 °C 4.1: sodium hydrogencarbonate / 1,4-dioxane; water / 0.5 h / 20 °C 4.2: 1 h 5.1: bis(sym-collidine)iodine(I) hexafluorophosphate / dichloromethane / 0.5 h / 20 °C 6.1: N-bromosuccinmide; boron trifluoride diethyl etherate / dichloromethane / 0.25 h / 0 °C View Scheme
参考文献
Okitsu, Takashi; Sato, Kana; Potewar, Taterao M.; Wada, Akimori
Journal of Organic Chemistry, 2011 , vol. 76, # 9 p. 3438 - 3449
反应条件
boron trifluoride diethyl etherate in 1,4-dioxane T=0 - 5°C; 10 h;
参考文献
Grigorian, S. G.; Avetisyan, K. G.; Matnishyan, A. A.
Journal of Organic Chemistry USSR (English Translation), 1986 , vol. 22, # 8 p. 1428 - 1430
Zhurnal Organicheskoi Khimii, 1986 , vol. 22, # 8 p. 1587 - 1591
反应条件
1.1: carbon tetrabromide / dichloromethane / 0.17 h / 0 °C 1.2: 2.17 h / 0 - 20 °C 2.1: potassium carbonate / N,N-dimethyl-formamide / 4 h / 20 °C View Scheme
参考文献
Robin, Sylvie; Rousseau, Gerard
European Journal of Organic Chemistry, 2000 , # 17 p. 3007 - 3011
反应条件
1: CuI 2: 34 percent / I2 3: 86 percent / MnO2 / CHCl3 / 20 °C 4: 50 percent / MnO2; NaCN / acetic acid / 20 °C 5: 55 percent / Pd(OAc)2; Na2CO3; LiCl / dimethylformamide / 15 h / 100 °C View Scheme
参考文献
Larock, Richard C.; Doty, Mark J.; Han, Xiaojun
Journal of Organic Chemistry, 1999 , vol. 64, # 24 p. 8770 - 8779
反应条件
[2,2']bipyridinyl; copper(l) iodide; 2,2,6,6-tetramethyl-1-piperidinyloxy, free radical in acetonitrile T=25 - 30°C; 12 h;
参考文献
Tian, Haiwen; Yu, Xiaochun; Li, Qiang; Wang, Jianxin; Xu, Qing
Advanced Synthesis and Catalysis, 2012 , vol. 354, # 14-15 p. 2671 - 2677,7
反应条件
1: tetrahydrofuran; cyclohexane / 19 h / 80 °C 3: 99 percent / m-CPBA / 0 - 21 °C View Scheme
参考文献
Forgione, Pat; Wilson, Peter D.; Fallis, Alex G.
Tetrahedron Letters, 2000 , vol. 41, # 1 p. 17 - 20
反应条件
hydrogen; poly(amidoamine) dendron-stabilised Pd(0) nanoparticle in dichloromethane T=25°C; P=760.051 Torr; 3 h;
参考文献
Chemical Communications, , # 2 p. 241 - 243
反应条件
1: With lithium hydride in tetrahydrofuran T=0°C; alcoholate formation; 1 h; 2: With lithium aluminium tetrahydride; cerium(III) chloride in tetrahydrofuran T=-78 - -20°C; Addition; 24 h;
参考文献
Bartoli, Giuseppe; Bellucci, M. Cristina; Bosco, Marcella; Dalpozzo, Renato; De Nino, Antonio; Sambri, Letizia; Tagarelli, Antonio
European Journal of Organic Chemistry, 2000 , # 1 p. 99 - 104
反应条件
hydrogen in chloroform-d1 T=25°C; 4 h; Catalytic behavior;
参考文献
RSC Advances, , vol. 3, # 33 p. 13642 - 13645
反应条件
oxygen; 2,3-dicyano-5,6-dichloro-p-benzoquinone; sodium nitrite in dichloromethane; acetic acid T=20°C; 3 h;
参考文献
Journal of Organic Chemistry, , vol. 77, # 1 p. 790 - 794
