2alpha-甲基环丁酮合成路线 （共 28 条）
反应条件
1: SOCl2
2: benzene
3: LiAlH4 / diethyl ether / Heating
4: (i) H2O2, (ii) (pyrolysis)
5: O3, Py / CH2Cl2
View Scheme
参考文献
Conia,J.-M.; Gore,J.
Bulletin de la Societe Chimique de France, 1963 , p. 735 - 743
反应条件
1: benzene
2: LiAlH4 / diethyl ether / Heating
3: (i) H2O2, (ii) (pyrolysis)
4: O3, Py / CH2Cl2
View Scheme
参考文献
Conia,J.-M.; Gore,J.
Bulletin de la Societe Chimique de France, 1963 , p. 735 - 743
反应条件
1: LiAlH4 / diethyl ether / Heating
2: (i) H2O2, (ii) (pyrolysis)
3: O3, Py / CH2Cl2
View Scheme
参考文献
Conia,J.-M.; Gore,J.
Bulletin de la Societe Chimique de France, 1963 , p. 735 - 743
反应条件
1: (i) H2O2, (ii) (pyrolysis)
2: O3, Py / CH2Cl2
View Scheme
参考文献
Conia,J.-M.; Gore,J.
Bulletin de la Societe Chimique de France, 1963 , p. 735 - 743
反应条件
1: Py / 0 °C
2: CF3CO2Na / trifluoroacetic acid / 264 h / 50 °C
View Scheme
参考文献
Hanack,M. et al.
Justus Liebigs Annalen der Chemie, 1970 , vol. 733, p. 5 - 26
反应条件
sodium carbonate in water
T=25°C; 24 h; other buffers; percent rearrangement in different solvents; Product distribution;
参考文献
Hanack, Michael; Collins, Clair J.; Stutz, H.; Benjamin, Ben M.
Journal of the American Chemical Society, 1981 , vol. 103, # 9 p. 2356 - 2360
反应条件
magnesium oxide
T=260°C; 5 h; Autoclave;
参考文献
Zhi, Chen; Dudu, Wu
Bulletin of the Korean Chemical Society, 2012 , vol. 33, # 6 p. 1834 - 1838
反应条件
magnesium oxide
T=260°C; 5 h; Autoclave;
参考文献
Zhi, Chen; Dudu, Wu
Bulletin of the Korean Chemical Society, 2012 , vol. 33, # 6 p. 1834 - 1838
