1,1,3-三苯基-2-丙炔醇合成路线 （共 48 条）
反应条件
2: benzene / Irradiation View Scheme
参考文献
Halton,B. et al.
Journal of the American Chemical Society, 1971 , vol. 93, # 9 p. 2327 - 2329
反应条件
1: With anhydrous iron chloride in chlorobenzene
T=60°C; 1 h;
2: With caesium carbonate in chlorobenzene
T=100°C; 3 h; Mechanism; Reagent/catalystSolvent; regioselective reaction;
参考文献
Hao, Lu; Hong, Jun-Jie; Zhu, Jun; Zhan, Zhuang-Ping
Chemistry - A European Journal, 2013 , vol. 19, # 18 p. 5715 - 5720
反应条件
1: anhydrous iron chloride / chlorobenzene / 1 h / 60 °C
2: caesium carbonate / chlorobenzene / 1 h / 60 °C
View Scheme
参考文献
Hao, Lu; Hong, Jun-Jie; Zhu, Jun; Zhan, Zhuang-Ping
Chemistry - A European Journal, 2013 , vol. 19, # 18 p. 5715 - 5720
反应条件
triethylamine; triphenylphosphine; palladium (II) trifluoroacetate in acetonitrile
T=80°C; 24 h;
参考文献
Wei, Li-Mei; Wei, Li-Lan; Pan, Wen-Bin; Wu, Ming-Jung
Synlett, 2005 , # 14 art. no. U10905ST, p. 2219 - 2223
反应条件
mercury(II) p-toluensulfonamidate; water in methanol
T=130°C; P=6000.6 Torr; 27 h; Inert atmosphereMicrowave irradiation; Overall yield = 93 percent; regioselective reaction;
参考文献
Corominas, Albert; Montana, Angel M.
Synthetic Communications, 2013 , vol. 43, # 15 p. 2062 - 2072
反应条件
titanium tetrachloride in dichloromethane
T=-40°C; 6 h;
参考文献
Karunakar, Galla V.; Periasamy, Mariappan
Journal of Organic Chemistry, 2006 , vol. 71, # 19 p. 7463 - 7466
反应条件
KSF clay
0.0833333 h; Irradiationmicrowave irradiation;
参考文献
Alloum, Abdelkrim Ben; Labiad, Bouchta; Villemin, Didier
Journal of the Chemical Society, Chemical Communications, 1989 , # 7 p. 386 - 387
反应条件
pyridinium p-toluenesulfonate in acetonitrile
T=20°C; 1 h;
参考文献
Sanz, Roberto; Martinez, Alberto; Alvarez-Gutierrez, Julia M.; Rodriguez, Felix
European Journal of Organic Chemistry, 2006 , # 6 p. 1383 - 1386
反应条件
mercury(II) p-toluensulfonamidate; water in methanol
T=130°C; P=6000.6 Torr; 27 h; Inert atmosphereMicrowave irradiation; Overall yield = 93 percent; regioselective reaction;
参考文献
Corominas, Albert; Montana, Angel M.
Synthetic Communications, 2013 , vol. 43, # 15 p. 2062 - 2072
参考文献
Weltzien; Micheel; Hess
Justus Liebigs Annalen der Chemie, 1923 , vol. 433, p. 257
