in not given under N2; by a react. of Ge-contg. compd. with Fe2(CO)9;
参考文献
Wetherby Jr., Anthony E.; Goeller, Lindy R.; DiPasquale, Antonio G.; Rheingold, Arnold L.; Weinert, Charles S.
Inorganic Chemistry, 2007 , vol. 46, # 18 p. 7579 - 7586
in 1,3,5-trimethyl-benzene byproducts: CO; Ar atmosphere, heating (boiling); isomer mixt. (4-3''-η4/3'-4'η4 82:18) not separated, total yield 49percent; elem. anal.;
triphenyl phosphine; benzophenone ketyl in not given
byproducts: Fe(CO)3(PPh3)2; inert gas; 293 K; a small amount bezophenone ketyl was added to a solution of the metal complex and the P-compound; solvent was removed; chromatographed;
参考文献
Arewgoda, Malini; Robinson, Brian H.; Simpson, Jim
Journal of the American Chemical Society, 1983 , vol. 105, # 7 p. 1893 - 1903
triphenylphosphine in tetrahydrofuran
under N2, mixt. of Fe-complex, 4-BrC6H4NSO and PPh3 (molar ratio 1:1:2)in THF were stirred for 1-4 h at room temp.; filtered, recrystd. from ether-MeOH or CH2Cl2-hexane; elem. anal.;
参考文献
Ashton, Henry C.; Manning, A. R.
Inorganic Chemistry, 1983 , vol. 22, p. 1440 - 1445
triphenylphosphine in tetrahydrofuran
under N2, mixt. of Fe-complex, C6H4NSO and PPh3 (molar ratio 1:1:2) in THF were stirred for 1-4 h at room temp.; solvent removed at reduced pressure, chromd. on alumina column (CH2Cl2), recrystd. from CH2Cl2-hexane; elem. anal.;
参考文献
Ashton, Henry C.; Manning, A. R.
Inorganic Chemistry, 1983 , vol. 22, p. 1440 - 1445
triphenylphosphine in tetrahydrofuran
under N2, mixt. of Fe-complex, 4-ClC6H4NSO and PPh3 (molar ratio 1:1:2)in THF were stirred for 1-4 h at room temp.; filtered, recrystd. from ether-MeOH or CH2Cl2-hexane; elem. anal.;
参考文献
Ashton, Henry C.; Manning, A. R.
Inorganic Chemistry, 1983 , vol. 22, p. 1440 - 1445
triphenylphosphine in tetrahydrofuran
under N2, mixt. of Fe-complex, 4-FC6H4NSO and PPh3 (molar ratio 1:1:2) in THF were stirred for 1-4 h at room temp.; filtered, recrystd. from ether-MeOH or CH2Cl2-hexane; elem. anal.;
参考文献
Ashton, Henry C.; Manning, A. R.
Inorganic Chemistry, 1983 , vol. 22, p. 1440 - 1445
