1,4,8,12-四氮杂环十五烷合成路线 （共 10 条）
反应条件
sulfuric acid T=100 - 105°C; Heating50-70 h;
参考文献
Luk'yanenko, N. G.; Basok, S. S.; Filonova, L. K.; Kulikov, N. V.; Pastushok, V. N.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1990 , vol. 26, # 3 p. 346 - 349
Khimiya Geterotsiklicheskikh Soedinenii, 1990 , # 3 p. 401 - 404
反应条件
1: 85 percent / tetrabutylammonium iodide, sodium hydroxide (50 percent) / toluene; H2O / 9 h / Heating 2: 60 percent / sulfuric acid, (conc.) / 39 h / 100 °C View Scheme
参考文献
Journal of Organic Chemistry USSR (English Translation), , vol. 24, p. 1562 - 1571
Zhurnal Organicheskoi Khimii, , vol. 24, # 8 p. 1731 - 1742
反应条件
ammonia; sodium in tetrahydrofuran T=-33°C; 2 h; Yield given;
参考文献
Tetrahedron Letters, , vol. 33, # 38 p. 5505 - 5508
反应条件
1: 95 percent / K2CO3 / dimethylformamide / 4 h / 110 °C 2: sodium, liquid ammonia / tetrahydrofuran / 2 h / -33 °C View Scheme
参考文献
Tetrahedron Letters, , vol. 33, # 38 p. 5505 - 5508
反应条件
1: 91 percent / sodium hydroxide / H2O / 1.) 1 hr., 5 deg C, 2.) r.t., 3 hrs. 2: 85 percent / tetrabutylammonium iodide, sodium hydroxide (50 percent) / toluene; H2O / 9 h / Heating 3: 60 percent / sulfuric acid, (conc.) / 39 h / 100 °C View Scheme
参考文献
Journal of Organic Chemistry USSR (English Translation), , vol. 24, p. 1562 - 1571
Zhurnal Organicheskoi Khimii, , vol. 24, # 8 p. 1731 - 1742
反应条件
in perchloric acid Kinetics; (N2); decompn. of Cr complex in 1 M HClO4 depending on temp. under anaerobic conditions; not isolated, monitored by UV;
参考文献
Inorganic Chemistry, , vol. 25, p. 478 - 484
反应条件
in perchloric acid Kinetics; (N2); decompn. of Cr complex in 1 M HClO4 depending on temp. under anaerobic conditions; not isolated, monitored by UV;
参考文献
Inorganic Chemistry, , vol. 25, p. 478 - 484
参考文献
Inorganic Chemistry, , vol. 19, p. 535 - 538
反应条件
1: With formic acid in water
T=20°C; Inert atmosphereReflux;
2: With sodium hydroxide in water
pH=12; Cooling with ice;
参考文献
Namuswe, Frances; Hayashi, Takahiro; Jiang, Yunbo; Kasper, Gary D.; Narducci Sarjeant, Amy A.; Moenne-Loccoz, Pierre; Goldberg, David P.
Journal of the American Chemical Society, 2010 , vol. 132, # 1 p. 157 - 167
反应条件
formaldehyd; formic acid
参考文献
Monsanto Company
Patent: US5610293 A1, 1997 ;
