顺,顺-1,5-环辛二烯合成路线 （共 287 条）
反应条件
48 h; Ambient temperaturealso with bis(trifluoromethyl)amino-oxyl; further dienes and times; Product distributionMechanism;
参考文献
Connelly, Gregory D.; Tipping, Anthony E.
Journal of Fluorine Chemistry, 1995 , vol. 71, # 1 p. 85 - 100
反应条件
1: m-CPBA, NaHCO3
2: aq. H2SO4
3: pyridine
5: K2CO3, methanol
6: 90 percent / H2 / 5percent Pd/C / methanol
View Scheme
参考文献
Horikawa, Tamaki; Norimine, Yoshihiko; Tanaka, Masakazu; Sakai, Kiyoshi; Suemune, Hiroshi
Chemical and Pharmaceutical Bulletin, 1998 , vol. 46, # 1 p. 17 - 21
反应条件
1: 55 g / Me4Sn / MoCl5/SiO2 / toluene / 24 h / 20 °C
2: 90 percent / LiAlH4; Cp2ZrCl2 / tetrahydrofuran / 1 h / 20 °C
3: 55 percent / 9-BBN; t-BuOK / 2-methyl-propan-2-ol
4: 95 percent / LiAlH4 / tetrahydrofuran / 1 h / 50 °C
View Scheme
参考文献
Bykov; Butenko; Egupova; Finkelshtein
Russian Chemical Bulletin, 2000 , vol. 49, # 7 p. 1301 - 1304
反应条件
osmium(VIII) oxide in dichloromethane
T=20°C; 12 h; Title compound not separated from byproducts;
参考文献
Kawazoe; Furusho; Nakanishi; Takata
Synthetic Communications, 2001 , vol. 31, # 14 p. 2107 - 2112
反应条件
potassium permanganate; potassium carbonate in ethanol
参考文献
Powell,K.A. et al.
Tetrahedron, 1972 , vol. 28, p. 2019 - 2027
反应条件
48 h; Ambient temperaturealso with bis(trifluoromethyl)amino-oxyl; further dienes and times; Product distributionMechanism;
参考文献
Connelly, Gregory D.; Tipping, Anthony E.
Journal of Fluorine Chemistry, 1995 , vol. 71, # 1 p. 85 - 100
反应条件
palladium diacetate in acetic acid
T=20°C; 48 h;
参考文献
Cramer, Nicolai; Buchweitz, Maria; Laschat, Sabine; Frey, Wolfgang; Baro, Angelika; Mathieu, Daniel; Richter, Christian; Schwalbe, Harald
Chemistry - A European Journal, 2006 , vol. 12, # 9 p. 2488 - 2503
反应条件
palladium diacetate; acetic acid
36 h; Ambient temperature;
参考文献
Perard-Viret; Rassat
Tetrahedron Asymmetry, 1994 , vol. 5, # 1 p. 1 - 4
反应条件
lead(IV) acetate; lithium chloride; palladium dichloride
50 h;
参考文献
Chernyuk, K. Yu.; Mel'nikova, V. I.; Pivnitskii, K. K.
Journal of Organic Chemistry USSR (English Translation), 1982 , vol. 18, p. 503 - 507
Zhurnal Organicheskoi Khimii, 1982 , vol. 18, # 3 p. 577 - 582
反应条件
in further solvent(s)
equimolar mixture was heated in diethylbenzene at 135°C for 24 h; inert atm.; evapn., chromy. (alumina column, petroleum ether, then benzene/chloroform);
参考文献
Slocum, D. W.; Engelmann, Theodore R.; Fellows, Robert L.; Moronski, Marek; Duraj, Stan
Journal of Organometallic Chemistry, 1984 , vol. 260, # 1 p. C21 - C25
