反式-1,2-二氯乙烯合成路线 (共 182 条)
反应条件
in monofluoro-trichloromethane T=-78°C; competition with ClFC=CFCl and HClC=CClH(trans), relative addition rates and orientation ratios; Rate constantProduct distribution;
参考文献
Navarrini, W.; Russo, A.; Tortelli, V.
Journal of Organic Chemistry, 1995 , vol. 60, # 20 p. 6441 - 6443
反应条件
N-butylamine; copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) in benzene 14 h; Ambient temperature;
参考文献
Tetrahedron Letters, , vol. 26, # 6 p. 709 - 712
参考文献
ATOCHEM NORTH AMERICA, INC.
Patent: EP401493 B1, 1994 ;
反应条件
1: trans-1,2-dichloroethylene With n-butyllithium in tetrahydrofuran; hexane T=0°C; 2: cyclohexanone in tetrahydrofuran; hexane T=0°C; 3: cyclohexanone Further stages;
参考文献
Nagaki, Aiichiro; Matsuo, Chika; Kim, Songhee; Saito, Kodai; Miyazaki, Atsuo; Yoshida, Jun-Ichi
Angewandte Chemie - International Edition, 2012 , vol. 51, # 13 p. 3245 - 3248
反应条件
fluorine in various solvent(s) T=-75°C; 8 h; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Conte, L.; Gambaretto, G. P.; Napoli, M.; Gervasutti, C.
Journal of Fluorine Chemistry, 1988 , vol. 38, p. 319 - 326
反应条件
fluorine in various solvent(s) T=-75°C; 8 h; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Conte, L.; Gambaretto, G. P.; Napoli, M.; Gervasutti, C.
Journal of Fluorine Chemistry, 1988 , vol. 38, p. 319 - 326
反应条件
hydrogenchloride; Schwartz's reagent; 2,2,6,6-tetramethylpiperidinyl-lithium Yield givenMultistep reaction;
参考文献
Kasatkin, Aleksandr; Whitby, Richard J.
Journal of the American Chemical Society, 1999 , vol. 121, # 30 p. 7039 - 7049
反应条件
piperidine; copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran T=20°C;
参考文献
Polhuis, Michael; Hendrikx, Cindy C. J.; Zuilhof, Han; Sudhoelter, Ernst J. R.
Tetrahedron Letters, 2003 , vol. 44, # 5 p. 899 - 901
反应条件
water; oxygen Decomposition; 0.0152778 h; UV-irradiation; Quantum yield;
参考文献
Guertler; Moeller; Sommer; Mueller; Kleinermanns
Chemosphere, 1994 , vol. 29, # 8 p. 1671 - 1682
反应条件
T=47°C; 20 h; Further byproducts given. Yields of byproduct given;
参考文献
Journal of Organic Chemistry USSR (English Translation), , vol. 23, # 6 p. 1129 - 1135
Zhurnal Organicheskoi Khimii, , vol. 23, # 6 p. 1248 - 1255