环己酮-2,4-二硝基苯腙合成路线 （共 16 条）
反应条件
sulfuric acid in ethanol; water
参考文献
BAXTER INTERNATIONAL INC.; BAXTER HEALTHCARE S.A.
Patent: WO2006/19855 A1, 2006 ;
Location in patent: Page/Page column 25 ;
反应条件
1: cyclohexanol With 1-methyl-1H-imidazole; [Cu(MeCN)]4*CF3SO3; 4,4'-dimethoxy-2,2'-bipyridine; ABNO; oxygen in acetonitrile T=20°C; 1 h; 2: (2,4-dinitro-phenyl)-hydrazine With hydrogenchloride in water; acetonitrile 1 h; Kinetics; Reagent/catalyst;
参考文献
Steves, Janelle E.; Stahl, Shannon S.
Journal of the American Chemical Society, 2013 , vol. 135, # 42 p. 15742 - 15745
反应条件
1: cyclohexylamine With lithium perchlorate; [3-amino-2,4-dihydroxyphenyl]phenylmethanone in methanol T=20°C; Electrochemical reaction; 2: (2,4-dinitro-phenyl)-hydrazine With sulfuric acid; lithium perchlorate in methanol; ethanol 1 h;
参考文献
Largeron, Martine; Neudorffer, Anne; Fleury, Maurice-Bernard
Angewandte Chemie - International Edition, 2003 , vol. 42, # 9 p. 1026 - 1029
反应条件
1: R(1+)*BF4(1-); air / acetonitrile / 16 h / UV-irradiation 2: HCl / acetonitrile; diethyl ether; H2O View Scheme
参考文献
Journal of Organic Chemistry, , vol. 70, # 24 p. 9780 - 9788
反应条件
hydrogenchloride in diethyl ether
参考文献
Journal of Organic Chemistry, , vol. 69, # 26 p. 9184 - 9190
反应条件
1: diluted alcohol View Scheme
参考文献
Journal of the American Chemical Society, , vol. 52, p. 2956
Organic Syntheses, , vol. Coll. Vol. II, p. 228
反应条件
hydrogen; boric acid; acetone; W-2 Raney-Ni 1.) THF, methanol, water, 25 deg C, 4 h; Yield given. Multistep reaction;
参考文献
Journal of Organic Chemistry, , vol. 49, p. 1654 - 1656
反应条件
sulfuric acid in methanol
参考文献
Journal of Organic Chemistry, , vol. 66, # 26 p. 8983 - 8991
反应条件
tetrafluoroboric acid; [Fe(bipy)3]2+ 1.) acetonitrile, water, r.t., 5 min; 2.) EtOH; Yield given. Multistep reaction;
参考文献
Chemical and Pharmaceutical Bulletin, , vol. 34, # 9 p. 3595 - 3598
反应条件
1: 85 percent / benzene / 6 h / Ambient temperature; Irradiation 2: H2O View Scheme
参考文献
Canadian Journal of Chemistry, , vol. 61, p. 400 - 410
