反式-1-苯基-1-戊烯合成路线 （共 108 条）
反应条件
(CuOTf)2.C6H6; (R,S,S)-(1,1'-spirobiindane-7,7'-diyloxy)=P-(N[PhCH(CH3)]2) in hexane; diethylene glycol dimethyl ether
T=-30°C; 24 h; Title compound not separated from byproducts;
参考文献
Shi, Wen-Jian; Wang, Li-Xin; Fu, Yu; Zhu, Shou-Fei; Zhou, Qi-Lin
Tetrahedron Asymmetry, 2003 , vol. 14, # 24 p. 3867 - 3872
反应条件
ytterbium(III) triflate
T=60°C; 8 h;
参考文献
Curini, Massimo; Epifano, Francesco; Maltese, Federica; Marcotullio, Maria Carla
European Journal of Organic Chemistry, 2003 , # 9 p. 1631 - 1634
反应条件
1: 59 percent / n-BuLi, HBr / tetrahydrofuran; hexane / 0.25 h / -45 °C
2: NaHMDS / tetrahydrofuran / -78 deg C -> 23 deg C
View Scheme
参考文献
Maryanoff,B.E.; Reitz,A.B.; Mutter,M.S.
Journal of the American Chemical Society, 1986 , vol. 108, p. 7664
反应条件
boron trifluoride diethyl etherate in hexane
0.5 h; Heating;
参考文献
Kabalka, George W.; Li, Nan-Sheng; Tejedor, David; Malladi, Rama R.; Trotman, Sarah
Journal of Organic Chemistry, 1999 , vol. 64, # 9 p. 3157 - 3161
反应条件
PO3(-)-TADDOL-(-)-N-methylephedrine in diethyl ether; dichloromethane
T=-78°C; 1 h; Product distribution; Further Variations:ReagentsSolventsTemperatures;
参考文献
Alexakis; Malan; Lea; Benhaim; Fournioux
Synlett, 2001 , # SPEC. ISS p. 927 - 930
反应条件
bis(acetylacetonato) palladium in tetrahydrofuran
T=25°C; 1 h;
参考文献
Naitoh, Yoshitaka; Bando, Fumiaki; Terao, Jun; Otsuki, Kazutaka; Kuniyasu, Hitoshi; Kambe, Nobuaki
Chemistry Letters, 2007 , vol. 36, # 2 p. 236 - 237
反应条件
2,4-dinitrobenzenesulfonic acid hydrate
T=80°C; Ritter reaction; 48 h;
参考文献
Sanz, Roberto; Martinez, Alberto; Guilarte, Veronica; Alvarez-Gutierrez, Julia M.; Rodriguez, Felix
European Journal of Organic Chemistry, 2007 , # 28 p. 4642 - 4645
反应条件
boron trifluoride in hexane
1 h; Heating; Yield given. Yields of byproduct given;
参考文献
Kabalka, George W.; Tejedor, David; Li, Nan-Sheng; Malladi, Rama R.; Trotman, Sarah
Tetrahedron, 1998 , vol. 54, # 51 p. 15525 - 15532
反应条件
hydrogen; Pd-HT1 in toluene
T=24.85°C; P=7500.6 Torr; 2 h; Product distribution; Further Variations:Catalysts;
参考文献
Mastalir, Agnes; Kiraly, Zoltan
Journal of Catalysis, 2003 , vol. 220, # 2 p. 372 - 381
反应条件
tricresyl phosphate in octane
T=195 - 200°C; 10 h;
参考文献
Schade, Peter; Schaefer, Thomas; Muellen, Klaus; Bender, Dietmar; Knoll, Konrad; Bronstert, Klaus
Chemische Berichte, 1991 , vol. 124, # 12 p. 2833 - 2842
