反式-1-苯基-1-戊烯合成路线 （共 108 条）
反应条件
in hexane; dichloromethane
T=35°C; 16 h; Inert atmosphere;
参考文献
Komanduri, Venukrishnan; Pedraza, Fernando; Krische, Michael J.
Advanced Synthesis and Catalysis, 2008 , vol. 350, # 10 p. 1569 - 1576
反应条件
in hexane; dichloromethane
T=35°C; 16 h; Inert atmosphere;
参考文献
Komanduri, Venukrishnan; Pedraza, Fernando; Krische, Michael J.
Advanced Synthesis and Catalysis, 2008 , vol. 350, # 10 p. 1569 - 1576
反应条件
potassium thioacyanate in methanol; water
50 h; Heating;
参考文献
Schwan, Adrian L.; Roche, Michael R.; Gallagher, John F.; Ferguson, George
Canadian Journal of Chemistry, 1994 , vol. 72, # 2 p. 312 - 324
反应条件
boron trifluoride in hexane
1 h; Heating; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Kabalka, George W.; Tejedor, David; Li, Nan-Sheng; Malladi, Rama R.; Trotman, Sarah
Journal of Organic Chemistry, 1998 , vol. 63, # 19 p. 6438 - 6439
反应条件
1: 83 percent / BuLi
2: 87 percent / sodium borohydride / ethanol
3: 89 percent / NaH / dimethylformamide
View Scheme
参考文献
Buss, Antony D.; Mason, Ralph; Warren, Stuart
Tetrahedron Letters, 1983 , vol. 24, # 47 p. 5293 - 5296
反应条件
1: pyridine / dichloromethane / 3 h / 0 - 20 °C / Inert atmosphere
2: (S)-2-((4-benzyl-1-(2,6-diisopropylphenyl)-4,5-dihydro-1H-imidazol-3-ium-3-yl)methyl)benzenesulfonate / diethyl ether / 17 h / -15 °C / Inert atmosphere
View Scheme
参考文献
Latham, Christopher M.; Blake, Alexander J.; Lewis, William; Lawrence, Matthew; Woodward, Simon
European Journal of Organic Chemistry, 2012 , # 4 p. 699 - 707
反应条件
lithium hexamethyldisilazane in tetrahydrofuran
T=-30°C; Rate constantMechanism;
参考文献
Maryanoff,B.E.; Reitz,A.B.; Mutter,M.S.
Journal of the American Chemical Society, 1986 , vol. 108, p. 7664
反应条件
in tetrahydrofuran
T=25°C; 2 h; Title compound not separated from byproducts;
参考文献
Jeganathan, Suruliappa; Tsukamoto, Masamitsu; Schlosser, Manfred
Synthesis, 1990 , # 2 p. 109 - 111
反应条件
in tetrahydrofuran
T=25°C; 2 h; Title compound not separated from byproducts;
参考文献
Jeganathan, Suruliappa; Tsukamoto, Masamitsu; Schlosser, Manfred
Synthesis, 1990 , # 2 p. 109 - 111
反应条件
lithium hexamethyldisilazane in tetrahydrofuran
T=-30°C; MechanismRate constant;
参考文献
Maryanoff,B.E.; Reitz,A.B.; Mutter,M.S.
Journal of the American Chemical Society, 1986 , vol. 108, p. 7664
