反式-1-苯基-1-戊烯合成路线 （共 108 条）
反应条件
in dimethyl sulfoxide; 1,2-dichloro-benzene
T=80°C; 7 h; Title compound not separated from byproducts;
参考文献
Liu, Michael T. H.; Choe, Yoong-Kee; Kimura, Masahiro; Kobayashi, Kaoru; Nagase, Shigeru; Wakahara, Takatsugu; Niino, Yasuyuki; Ishitsuka, Midori O.; Maeda, Yutaka; Akasaka, Takeshi
Journal of Organic Chemistry, 2003 , vol. 68, # 19 p. 7471 - 7478
反应条件
1: 1.) n-BuLi / 1.) THF, 0 deg C, 30 min; 2.) -78 deg C -> -50 deg C, 10 min
2: NaH / dimethylformamide; various solvent(s)
View Scheme
参考文献
Buss, Antony D.; Warren, Stuart
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1985 , p. 2307 - 2326
反应条件
1: 1.) pyridine; 2.) I2 / 1.) ether, -78 deg C, 1.5 h, 25 deg C, 45 min; 2.) toluene, reflux, 24 h
2: 1.) n-BuLi / 1.) THF, 0 deg C, 30 min; 2.) -78 deg C -> -50 deg C, 10 min
3: NaH / dimethylformamide; various solvent(s)
View Scheme
参考文献
Buss, Antony D.; Warren, Stuart
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1985 , p. 2307 - 2326
反应条件
sodium hydride in N,N-dimethyl-formamide
参考文献
Buss, Antony D.; Warren, Stuart
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1985 , p. 2307 - 2326
反应条件
in tetrahydrofuran
T=25°C; 2 h; Title compound not separated from byproducts;
参考文献
Jeganathan, Suruliappa; Tsukamoto, Masamitsu; Schlosser, Manfred
Synthesis, 1990 , # 2 p. 109 - 111
反应条件
in tetrahydrofuran
T=25°C; 2 h; Title compound not separated from byproducts;
参考文献
Jeganathan, Suruliappa; Tsukamoto, Masamitsu; Schlosser, Manfred
Synthesis, 1990 , # 2 p. 109 - 111
反应条件
in tetrahydrofuran
T=25°C; 2 h; Title compound not separated from byproducts;
参考文献
Jeganathan, Suruliappa; Tsukamoto, Masamitsu; Schlosser, Manfred
Synthesis, 1990 , # 2 p. 109 - 111
反应条件
in tetrahydrofuran
T=25°C; 2 h; Title compound not separated from byproducts;
参考文献
Jeganathan, Suruliappa; Tsukamoto, Masamitsu; Schlosser, Manfred
Synthesis, 1990 , # 2 p. 109 - 111
反应条件
in tetrahydrofuran
T=25°C; 2 h; Title compound not separated from byproducts;
参考文献
Jeganathan, Suruliappa; Tsukamoto, Masamitsu; Schlosser, Manfred
Synthesis, 1990 , # 2 p. 109 - 111
反应条件
1: SOCl2, Py / CHCl3
2: (i) Mg, Et2O, (ii) /BRN= 1730731/
View Scheme
参考文献
Lehmkuhl,H. et al.
Justus Liebigs Annalen der Chemie, 1975 , p. 119 - 144
