1,1-二甲基-2,5-二氢硅杂环戊二烯合成路线 （共 40 条）
反应条件
T=600°C; Further byproducts given;
参考文献
Conlin,R.T.; Huffaker,H.B.; Kwak,Y.W.
Journal of the American Chemical Society, 1985 , vol. 107, p. 731
反应条件
T=850°C; P=0.01 Torr;
参考文献
Marchand, Annette; Gerval, Pierre; Duboudin, Francoise; Gaufryau, M.-H.; Joanny, Marguerite; Mazerolles, Pierre
Journal of Organometallic Chemistry, 1984 , vol. 267, # 1 p. 93 - 106
反应条件
in diethyl ether
6 h; Heating;
参考文献
Heinicke, J.; Gehrhus, B.; Meinel, S.
Journal of Organometallic Chemistry, 1994 , vol. 474, # 1-2 p. 71 - 82
参考文献
Conlin, Robert T.; Wood, David L.
Journal of the American Chemical Society, 1981 , vol. 103, # 7 p. 1843 - 1844
反应条件
tungsten in octane; chlorobenzene
T=80°C; 0.333333 h;
参考文献
Leconte, Michel; Pagano, Salvatore; Mutch, Andrew; Lefebvre, Frederic; Basset, Jean Marie
Bulletin de la Societe Chimique de France, 1995 , vol. 132, # 10 p. 1069 - 1072
反应条件
sodium in tetrahydrofuran
参考文献
Weyenberg,D.R. et al.
Journal of Organic Chemistry, 1968 , vol. 33, # 5 p. 1975 - 1982
反应条件
T=670°C; Further byproducts given;
参考文献
Conlin,R.T.; Huffaker,H.B.; Kwak,Y.W.
Journal of the American Chemical Society, 1985 , vol. 107, p. 731
反应条件
in nitric acid
byproducts: H2SO4, NO, CO; stirring for 0.5 h at 25°C; condensing silane in a trap cooled with solid CO2, treating aq. layer with NaOH, evapn. to dryness, IR;
参考文献
Lebedev, A. V.; Kuz'min, O. V.; Chernyshev, E. A.
Journal of General Chemistry USSR (English Translation), 1986 , vol. 56, p. 1624 - 1627
Zhurnal Obshchei Khimii, 1986 , vol. 56, p. 1837 - 1840
反应条件
1: buta-1,3-diene With naphthalene; lithium in tert-butyl methyl ether
T=-2°C; 2.5 h; Inert atmosphere;
2: dimethyl-dichlorosilane in tert-butyl methyl ether
T=0 - 20°C; Inert atmosphere;
参考文献
Sabata; Blcchta; Karban; Pleska; Vcclak; Hetflcjs
Polish Journal of Chemistry, 2009 , vol. 83, # 11 p. 1953 - 1958
反应条件
in diethyl ether
2 h; Heating;
参考文献
Finkel'shtein, E. Sh.; Portnykh, E. B.; Ushakov, N. V.; Vdovin, V. M.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1981 , vol. 30, # 3 p. 483 - 487
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1981 , # 3 p. 641 - 645
