1,1-二甲基-2,5-二氢硅杂环戊二烯合成路线 （共 40 条）
反应条件
T=750°C; P=0.01 Torr; Further byproducts given;
参考文献
Marchand, Annette; Gerval, Pierre; Duboudin, Francoise; Gaufryau, M.-H.; Joanny, Marguerite; Mazerolles, Pierre
Journal of Organometallic Chemistry, 1984 , vol. 267, # 1 p. 93 - 106
参考文献
Bain,S.; Ijadi-Maghsoodi,S.; Barton,T.J.
Journal of the American Chemical Society, 1988 , vol. 110, p. 2611
反应条件
1: 83 percent / m-chloroperbenzoic acid / diethyl ether / 0 - 20 °C
2: 89 percent / LiAlH4 / diethyl ether / 3 h / Heating
3: HCl
View Scheme
参考文献
Boukherroub, Rabah; Manuel, Georges
Journal of Organometallic Chemistry, 2000 , vol. 604, # 2 p. 141 - 149
反应条件
in gas
T=453.3 - 485.4°C; P=3 Torr; KineticsProduct distribution;
参考文献
Conlin, Robert T.; Kwak, Young-Woo
Journal of the American Chemical Society, 1986 , vol. 108, # 4 p. 834 - 835
反应条件
tetrabutylstannane; aluminum oxide; Re2O7 in n-heptane
T=45°C; 3 h; other reagent; Product distribution;
参考文献
Finkel'shtein, E. Sh.; Portnykh, E. B.; Ushakov, N. V.; Vdovin, V. M.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1981 , vol. 30, # 3 p. 483 - 487
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1981 , # 3 p. 641 - 645
参考文献
Barton,T.J.; Wulff,W.D.
Journal of Organometallic Chemistry, 1979 , vol. 168, p. 23 - 31
反应条件
hydrogenchloride
protodesilylation;
参考文献
Boukherroub, Rabah; Manuel, Georges
Journal of Organometallic Chemistry, 2000 , vol. 604, # 2 p. 141 - 149
参考文献
Petrow et al.
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1955 , p. 947; engl. Ausg. S. 861
Zhurnal Obshchei Khimii, 1958 , vol. 28, p. 2085,2088; engl. Ausg. S. 2122, 2124
反应条件
T=530 - 590°C; ΔS(excit.), E(a); Thermodynamic data;
参考文献
Barton, Thomas J.; Lin, Jibing; Ijadi-Maghsoodi, Sina; Power, Martin D.; Zhang, Xianping; Ma, Zhongxin; Shimizu, Hideaki; Gordon, Mark S.
Journal of the American Chemical Society, 1995 , vol. 117, # 47 p. 11695 - 11703
反应条件
T=600°C; further temperature; Product distribution;
参考文献
Conlin,R.T.; Huffaker,H.B.; Kwak,Y.W.
Journal of the American Chemical Society, 1985 , vol. 107, p. 731
