in benzene-d6 react. of Fe complex and HSnMe3 in benzene, 60°C, 13 h; yields detd. by (1)H-NMR (C5H5Fe(CO)H(SnMe3)2; elem. anal.) and GL-chromy. (other products);
参考文献
Journal of the Chemical Society, Chemical Communications, , # 23 p. 1790 - 1792
in neat (no solvent)
addn. 1equiv. of tinhydride, excess of tinhydride no further reactn.; not isolated; identified 90percent SiF2H2, 5percent SiF3H and SiH4 in product mixt.;
参考文献
D'Errico, John J.; Sharp, Kenneth G.
Inorganic Chemistry, 1989 , vol. 28, p. 2177 - 2180
in neat (no solvent)
inert atmosphere (N2, Ar or high vac.), room temperature, three equiv. of tinhydride, reactn. time 0.5 h; not isolated; IR spectroscopy (identified 60percent SiH4, 20percent SiF3H and 20percent SiF2H2 in product mixt.);
参考文献
D'Errico, John J.; Sharp, Kenneth G.
Inorganic Chemistry, 1989 , vol. 28, p. 2177 - 2180
in neat (no solvent)
inert atmosphere (N2, Ar or high vac.), room temperature, equimolar amts. of halosilane/tinhydride, reactn. time 60 h; not isolated; IR spectroscopy (identified 95percent SiF3H, trace SiF2H2 and trace SiH4 in product mixt.);
参考文献
D'Errico, John J.; Sharp, Kenneth G.
Inorganic Chemistry, 1989 , vol. 28, p. 2177 - 2180
in neat (no solvent)
inert atmosphere (N2, Ar or high vac.), room temperature, equimolar amts. of halosilane/tinhydride, reactn. time 6-8 h; not isolated; IR spectroscopy (identified 95percent SiF3H, trace SiF2H2 and trace SiH4 in product mixt.);
参考文献
D'Errico, John J.; Sharp, Kenneth G.
Inorganic Chemistry, 1989 , vol. 28, p. 2177 - 2180
