2-甲基-5-己烯-2-醇合成路线 （共 29 条）
参考文献
Perkin; Pickles
Journal of the Chemical Society, 1905 , vol. 87, p. 657
反应条件
1: HCl / 20 h / 0 °C
2: 1) Mg / THF
3: LiAlH4 / diethyl ether / 0 °C
4: 6.6 g / Br2 / PPh3 / pyridine / 20 h / Heating
5: 9.8 percent Chromat. / LiAlH4 / tetrahydrofuran / 480 h / Ambient temperature
View Scheme
参考文献
Ashby, E. C.; DePriest, R. N.; Goel, A. B.; Wenderoth, Bernd; Pham, Tung N.
Journal of Organic Chemistry, 1984 , vol. 49, # 19 p. 3545 - 3556
反应条件
1: HCl / 20 h / 0 °C
2: 1) Mg / THF
3: LiAlH4 / diethyl ether / 0 °C
4: 93 percent / I2 / PPh3 / pyridine / benzene / 24 h / Heating
View Scheme
参考文献
Ashby, E. C.; DePriest, R. N.; Goel, A. B.; Wenderoth, Bernd; Pham, Tung N.
Journal of Organic Chemistry, 1984 , vol. 49, # 19 p. 3545 - 3556
反应条件
1: HCl / 20 h / 0 °C
2: 1) Mg / THF
3: LiAlH4 / diethyl ether / 0 °C
4: 60 percent / pyridine / benzene / 24 h / Ambient temperature
View Scheme
参考文献
Ashby, E. C.; DePriest, R. N.; Goel, A. B.; Wenderoth, Bernd; Pham, Tung N.
Journal of Organic Chemistry, 1984 , vol. 49, # 19 p. 3545 - 3556
反应条件
phosphorus tribromide in pyridine
参考文献
Bloodworth; Curtis; Spencer; Tallant
Tetrahedron, 1993 , vol. 49, # 13 p. 2729 - 2750
反应条件
1: HCl / 20 h / 0 °C
2: 1) Mg / THF
View Scheme
参考文献
Ashby, E. C.; DePriest, R. N.; Goel, A. B.; Wenderoth, Bernd; Pham, Tung N.
Journal of Organic Chemistry, 1984 , vol. 49, # 19 p. 3545 - 3556
反应条件
phosphoric acid
beim Destillieren;
参考文献
Colonge; Lagier
Bulletin de la Societe Chimique de France, 1949 , p. 16
参考文献
Colonge; Lagier
Bulletin de la Societe Chimique de France, 1949 , p. 16
反应条件
1: HCl / 20 h / 0 °C
2: 1) Mg / THF
3: LiAlH4 / diethyl ether / 0 °C
4: 6.6 g / Br2 / PPh3 / pyridine / 20 h / Heating
View Scheme
参考文献
Ashby, E. C.; DePriest, R. N.; Goel, A. B.; Wenderoth, Bernd; Pham, Tung N.
Journal of Organic Chemistry, 1984 , vol. 49, # 19 p. 3545 - 3556
