反应条件
in water
aq. NaBH4 was added to aq. solns. of Mo- and Ni-compd., stirring for 30 min, solid was washed 3 times with H2O then with EtOH, dried in vac. desiccator for 3 h, annealing at 550-795 K in He flow; monitored by XRD; at 795 K MoO2 started to crystallize;
参考文献
Parks, Greg L.; Pease, Melissa L.; Burns, Autumn W.; Layman, Kathryn A.; Bussell, Mark E.; Wang, Xianqin; Hanson, Jonathon; Rodriguez, Jose A.
Journal of Catalysis, 2007 , vol. 246, # 2 p. 277 - 292