1-甲基-1,2-环氧环己烷合成路线 （共 60 条）
反应条件
(i) 2,6-dimethyl-pyridine, toluene, (ii) DBU; Multistep reaction;
参考文献
Murata,S. et al.
Journal of the American Chemical Society, 1979 , vol. 101, p. 2738 - 2739
反应条件
lithium perchlorate in diethyl ether
2 h; Ambient temperature;
参考文献
Sudha; Malola Narasimhan; Geetha Saraswathy; Sankararaman
Journal of Organic Chemistry, 1996 , vol. 61, # 5 p. 1877 - 1879
反应条件
boron trifluoride diethyl etherate in chloroform
参考文献
Sugihara, Yoshiaki; Iimura, Shinya; Nakayama, Juzo
Chemical Communications, 2002 , # 2 p. 134 - 135
反应条件
1,3-dimethyl-imidazolidin-2-one; toluene-4-sulfonic acid in dichloromethane
T=20°C; 2 h; regioselective reaction;
参考文献
Chapman, Helen A.; Herbal, Karim; Motherwell, William B.
Synlett, 2010 , # 4 art. no. D37609ST, p. 595 - 598
反应条件
hydrogen; palladium on activated charcoal in isopropyl alcohol
T=20°C; P=760 Torr; 4 h; various solvents; MechanismProduct distribution;
参考文献
Accrombessi, Georges C.; Geneste, Patrick; Olive, Jean-Louis; Pavia, Andre A.
Journal of Organic Chemistry, 1980 , vol. 45, # 21 p. 4139 - 4143
反应条件
toluene-4-sulfonic acid in dichloromethane
T=20°C; 2 h; regioselective reaction;
参考文献
Chapman, Helen A.; Herbal, Karim; Motherwell, William B.
Synlett, 2010 , # 4 art. no. D37609ST, p. 595 - 598
反应条件
oxygen; deuterium
T=37.5°C; P=760 Torr; Irradiationgas-phase, add of Me3N, var. pressure; further reag: CH4; Product distributionMechanism;
参考文献
Cecchi, Patrizio; Cipollini, Romano; Pizzabiocca, Adriano; Renzi, Gabriele; Speranza, Maurizio
Tetrahedron, 1988 , vol. 44, # 15 p. 4847 - 4856
反应条件
sulfuric acid
0.0166667 h; Ambient temperature;
参考文献
Crotti, Paolo; Macchia, Franco; Pizzabiocca, Adriano; Renzi, Gabriele; Speranza, Maurizio
Gazzetta Chimica Italiana, 1987 , vol. 117, # 12 p. 739 - 746
反应条件
methane
T=37.5°C; Irradiationfurther 1,2-epoxycyclohexanes, radiolytical formed acids or nucleophiles; also with NMe3; Product distribution;
参考文献
Crotti, Paolo; Macchia, Franco; Pizzabiocca, Adriano; Renzi, Gabriele; Speranza, Maurizio
Gazzetta Chimica Italiana, 1987 , vol. 117, # 12 p. 739 - 746
参考文献
Tiffeneau; Tchoubar
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1938 , vol. 207, p. 918
