2,3-萘并-15-冠醚-5合成路线 （共 6 条）
反应条件
1: 2,3-dihydroxy-naphthalene With tetrabutylammomium bromide; sodium hydroxide in benzene T=60°C; 0.5 h; 2: tetraethylene glycol di-p-toluenesulfonate in benzene 15 h; Heating;
参考文献
Ganin, Eduard V.; Basok, Stepan S.; Yavolovskii, Arkadii A.; Botoshansky, Mark M.; Fonari, Marina S.
CrystEngComm, 2011 , vol. 13, # 2 p. 674 - 683
反应条件
sodium hydroxide; p-toluenesulfonyl chloride in 1,4-dioxane
参考文献
Czech, B.; Czech, A.; Bartsch, R. A.
Journal of Heterocyclic Chemistry, 1984 , vol. 21, p. 341 - 343
反应条件
1: conc. HCl / CH2Cl2; methanol / 1 h / Ambient temperature 2: 90 percent / NaOH, p-toluenesulfonyl chloride / dioxane View Scheme
参考文献
Journal of Heterocyclic Chemistry, , vol. 21, p. 341 - 343
反应条件
1: NaOH / butan-1-ol / 30 h / Heating 2: conc. HCl / CH2Cl2; methanol / 1 h / Ambient temperature 3: 90 percent / NaOH, p-toluenesulfonyl chloride / dioxane View Scheme
参考文献
Journal of Heterocyclic Chemistry, , vol. 21, p. 341 - 343
反应条件
in tetrahydrofuran 0.25 h; selectivity of reductive cleavage of the aryl-oxygen bonds; also for other arenocrown ethers;
参考文献
Sokol, Maria; Kowalczuk, Marek; Grobelny, Zbigniew; Janeczek, Henryk; Jedlinski, Zbigniew; et al.
Journal of Organic Chemistry, 1995 , vol. 60, # 8 p. 2365 - 2367
反应条件
in tetrahydrofuran 0.25 h; selectivity of reductive cleavage of the aryl-oxygen bonds; also for other arenocrown ethers;
参考文献
Sokol, Maria; Kowalczuk, Marek; Grobelny, Zbigniew; Janeczek, Henryk; Jedlinski, Zbigniew; et al.
Journal of Organic Chemistry, 1995 , vol. 60, # 8 p. 2365 - 2367
