NaOH in water
addn. of solution of benzene-1,2-dithiol and sodium hydroxide in nitrogen-purged water to a solution of methyltin trichloride in water (using trichloride : benzenedithiol = 7.0mmol : 4.6mmol; same product was obtained on using 1:1 ratio);; recrystn. from dichloromethyn/n-hexane mixture;;
参考文献
Peruzzo, Valerio; Plazzogna, Gualtiero; Bandoli, Giuliano
Journal of Organometallic Chemistry, 1991 , vol. 415, # 3 p. 335 - 341
1: 1,2-dimercaptobenzene With n-butyllithium; N,N,N',N,-tetramethylethylenediamine in hexane
T=20°C; 65 h;
2: With water-d2 in hexane
T=20°C; 1 h;
3: isopropyl bromide in methanol
24 h; Heating; Title compound not separated from byproducts;
参考文献
Huynh, Han Vinh; Seidel, Wolfram W.; Luegger, Thomas; Froehlich, Roland; Wibbeling, Birgit; Hahn, F. Ekkehardt
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 2002 , vol. 57, # 12 p. 1401 - 1408
