N-三甲基硅基苯甲醛亚胺合成路线 （共 59 条）
反应条件
1: 1. diisopropylamine, n-butyllithium / 1. THF, 2 h; 2. THF a.) -78 deg C, 4 h, b.) r.t. 2: 81 percent / tetra-n-butylammonium fluoride / tetrahydrofuran / 0.42 h / Ambient temperature 3: 100 percent / tetrahydrofuran / 2 h / 0 °C View Scheme
参考文献
Ojima, Iwao; Habus, Ivan; Zhao, Mangzhu; Zucco, Martine; Park, Young Hoon; Sun, Chung Ming; Brigaud, Thierry
Tetrahedron, 1992 , vol. 48, # 34 p. 6985 - 7012
反应条件
1: 80 percent / CHCl3 / 1 h / Heating 2: 68 percent / aq. K2CO3, oxone / CHCl3 / 0.75 h / 0 - 4 °C 3: CHCl3 / 1 h / Ambient temperature View Scheme
参考文献
Vidal, Joelle; Damestoy, Stephanie; Guy, Laure; Hannachi, Jean-Christophe; Aubry, Andre; Collet, Andre
Chemistry - A European Journal, 1997 , vol. 3, # 10 p. 1691 - 1709
反应条件
in chloroform 1 h; Heating;
参考文献
Journal of the Chemical Society, Chemical Communications, , # 6 p. 435 - 437
Chemistry - A European Journal, , vol. 3, # 10 p. 1691 - 1709
反应条件
1.1: titanium(IV) isopropylate; cyclopentyl-magnesium chloride / tetrahydrofuran; diethyl ether / 1.5 h / -78 - -30 °C / Inert atmosphere 1.2: 0.17 h / -78 - 0 °C / Inert atmosphere 1.3: 0 - 20 °C / Inert atmosphere 2.1: hydrogenchloride; boron trifluoride diethyl etherate; mercury(II) oxide / tetrahydrofuran; water / 100 °C / Inert atmosphere View Scheme
参考文献
Chen, Ming Z.; Micalizio, Glenn C.
Journal of the American Chemical Society, 2012 , vol. 134, # 2 p. 1352 - 1356
反应条件
1.1: titanium(IV) isopropylate; cyclopentyl-magnesium chloride / tetrahydrofuran; diethyl ether / 1.5 h / -78 - -30 °C / Inert atmosphere 1.2: 0.17 h / -78 - 0 °C / Inert atmosphere 1.3: 0 - 20 °C / Inert atmosphere 2.1: hydrogenchloride; boron trifluoride diethyl etherate; mercury(II) oxide / tetrahydrofuran; water / 100 °C / Inert atmosphere View Scheme
参考文献
Chen, Ming Z.; Micalizio, Glenn C.
Journal of the American Chemical Society, 2012 , vol. 134, # 2 p. 1352 - 1356
反应条件
2: aq. LiOH, 30percent aq. H2O2 / tetrahydrofuran / 15 h / 0 °C 3: diethyl ether; methanol View Scheme
参考文献
Gennari, Cesare; Vulpetti, Anna; Donghi, Monica; Mongelli, Nicola; Vanotti, Ermes
Angewandte Chemie, 1996 , vol. 108, # 15 p. 1809 - 1812
反应条件
1: TMS-N=CH-Ph With cyclohexylMgCl in tetrahydrofuran; diethyl ether T=-78 - -30°C; 1.53333 h; Ionic liquid; 2: C16H31O2Si(1-)*Li(1+) in tetrahydrofuran; diethyl ether T=-30 - 20°C; 2 h; Inert atmosphere; 3: benzophenone in tetrahydrofuran; diethyl ether T=-30 - 20°C; 3 h; Inert atmosphere;
参考文献
Chemical Communications, , vol. 49, # 78 p. 8857 - 8859
反应条件
in diethyl ether T=20°C; Addition; 0.5 h;
参考文献
Saidi, Mohammad R.; Javanshir, Shahrzad; Mojtahedi, Mohammad M.
Journal of Chemical Research - Part S, 1999 , # 5 p. 330 - 331
反应条件
1: Et3N / hexane; heptane; toluene / 0 - 20 °C 2: toluene / Heating 3: 79 percent / tris(trimethylsilyl)silane; AIBN / toluene / 2 h / 100 °C View Scheme
参考文献
Ha, Deok-Chan; Hart, David J.; Yang, Teng-Kuei
Journal of the American Chemical Society, 1984 , vol. 106, # 17 p. 4819 - 4825
反应条件
Yield given. Multistep reaction;
参考文献
Colvin, Ernest W.; McGarry, Daniel G.
Journal of the Chemical Society, Chemical Communications, 1985 , # 9 p. 539 - 540
