反应条件
N(CH2CH3)3 in tetrahydrofuran (N2); addn. of selenium compd. and amine to a soln. of iron carbonyl in THF, stirring at room temp. for 10 min, cooling to -100°C, pouring to manganese complex, warming to -80°C, stirring for 7-8 h at -80 to -45°C; evapn. at -50 to -40°C, column chromy (Al2O3, petroleum ether, petroleum ether/CH2Cl2 20:1, petroleum ether/CH2Cl2/Et2O 10:1:1), evapn., recrystn. (petroleum ether/CH2Cl2, -80°C); elem. anal.;
参考文献
Organometallics, , vol. 20, # 11 p. 2226 - 2233
