二氯(DPPE)二金(I)合成路线 （共 26 条）
反应条件
in acetone addn. of soln. of dppe (1 equiv.) in acetone to suspn. of (AuCl(SMe)2) (2 equiv.) in acetone; stirring for 2 h; pptn., filtration, washing with acetone, diethyl ether and pentane, drying under vac.;
参考文献
Brandys, Marie-Claude; Jennings, Michael C.; Puddephatt, Richard J.
Journal of the Chemical Society, Dalton Transactions, 2000 , # 24 p. 4601 - 4606
反应条件
in not given N2-atmosphere; stoich. amts.;
参考文献
Molter, Anja; Rust, Joerg; Lehmann, Christian W.; Deepa, Ganesh; Chiba, Peter; Mohr, Fabian
Dalton Transactions, 2011 , vol. 40, # 38 p. 9810 - 9820
反应条件
in benzene byproducts: CO; soln. of Ph2PCH2CH2PPh2 dropped to soln. of (OC)AuCl at room temp. under dry N2, stirred for 1 h (CO removed); filtered;
参考文献
Schmidbaur, Hubert; Inoguchi, Yoshio
Chemische Berichte, 1980 , vol. 113, # 5 p. 1646 - 1653
反应条件
1,2-bis-(diphenylphosphino)ethane in water; acetone addn. of thiodiglycol to NaAuCl4 in H2O/Me2CO, then addn. of phosphine (0.5 equiv.) in Me2CO (pptn.), stirring (30 min); filtration, washing (H2O), drying (vac.);
参考文献
Berners-Price, Susan; Sadler, Peter J.
Inorganic Chemistry, 1986 , vol. 25, p. 3822 - 3827
反应条件
in water; acetone Au-complex was reduced to Au(I) by thiodiglycol in aq. acetone, ligand in acetone was added dropwise over 5 min, stirred for 1 h; ppt. was filtered off, washed with H2O and acetone; elem. anal.;
参考文献
Berners-Price, Susan J.; Mazid, Muhammed A.; Sadler, Peter J.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1984 , p. 969 - 974
反应条件
Ph2P(CH2)2PPh2 in dichloromethane N2, 2 equivalents Au-complex, 1 equivalent ligand, stirring for 15 min;
参考文献
Brown, Scott S. D.; Salter, Ian D.; Dyson, David B.; Parish, R. V. ('Dick'); Bates, Paul A.; Hursthouse, Michael B.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1988 , p. 1795 - 1802
反应条件
1,2-bis(diphenylphosphino)ethane in ethanol; chloroform addn. of equimolar amt. of dppe (in CHCl3) to Au-complex (in acetone); filtration, concn., crystn. on cooling; elem. anal.;
参考文献
McAuliffe, Charles A.; Parish, R. V. (Dick); Randall, P. David
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1979 , p. 1730 - 1735
反应条件
in methanol; dichloromethane N2, stoich., a soln. of gold compd. (methanol) added to a soln. of phosphane (CH2Cl2), stirred for 24 h; solvent removed (vac.), water added, ppt. filtered, washed (water, diethyl ether), dried (vac.);
参考文献
Olkowska-Oetzel, Jolanta; Sevillano, Paloma; Eichhoefer, Andreas; Fenske, Dieter
European Journal of Inorganic Chemistry, 2004 , # 5 p. 1100 - 1106
反应条件
1: dichloromethane 2: neat (no solvent) View Scheme
参考文献
Vollano, Jean F.; Picker, Donald H.; Statler, John A.
Inorganica Chimica Acta, 1989 , vol. 155, p. 31 - 34
反应条件
in neat (no solvent) decomposition in presence of chloride;
参考文献
Vollano, Jean F.; Picker, Donald H.; Statler, John A.
Inorganica Chimica Acta, 1989 , vol. 155, p. 31 - 34
