7,8,15,16,23,24-六氧杂三螺(5.2.5.2.5.2)二十四烷合成路线 （共 21 条）
反应条件
dihydrogen peroxide; nitric acid in isopar G; water; acetic acid
T=15 - 20°C; 1.76667 - 2.25 h; Product distribution / selectivity;
参考文献
DEGUSSA INITIATORS GMBH and CO. KG
Patent: WO2004/76405 A1, 2004 ;
Location in patent: Page/Page column 6-8; sheet 1 ;
参考文献
McCullough, Kevin J.; Morgan, Alistair R.; Nonhebel, Derek C.; Pauson, Peter L.; White, Graham J.
Journal of Chemical Research, Miniprint, 1980 , # 2 p. 601 - 628
反应条件
dihydrogen peroxide; iodine in acetonitrile
T=18 - 22°C; 6 h;
参考文献
Terent'ev, Alexander O.; Borisov, Alexander M.; Platonov, Maxim M.; Starikova, Zoya A.; Chernyshev, Vladimir V.; Nikishin, Gennady I.
Synthesis, 2009 , # 24 art. no. P10509SS, p. 4159 - 4166
反应条件
1: 92 percent / 86percent H2O2, 3 M H2SO4 / 24 h / 20 °C
2: 89 percent / 3 M H2SO4 / 24 h / 20 °C
3: 75 percent / methanol
View Scheme
参考文献
McCullough, Kevin J.; Morgan, Alistair R.; Nonhebel, Derek C.; Pauson, Peter L.; White, Graham J.
Journal of Chemical Research, Miniprint, 1980 , # 2 p. 601 - 628
反应条件
1.1: potassium carbonate / 15 h / |Reflux
2.1: dichloromethane / 0.5 h / 0 °C
2.2: 24 h / 0 - 20 °C
View Scheme
参考文献
Neupane, Chiranjeev Sharma; Awasthi, Satish Kumar
Tetrahedron Letters, 2012 , vol. 53, # 45 p. 6067 - 6070,4
反应条件
1: 89 percent / 3 M H2SO4 / 24 h / 20 °C
2: 75 percent / methanol
View Scheme
参考文献
McCullough, Kevin J.; Morgan, Alistair R.; Nonhebel, Derek C.; Pauson, Peter L.; White, Graham J.
Journal of Chemical Research, Miniprint, 1980 , # 2 p. 601 - 628
反应条件
1: aqueous H2O2
2: copper (II)-sulfate
View Scheme
参考文献
Criegee; Schnorrenberg; Becke
Justus Liebigs Annalen der Chemie, 1949 , vol. 565, p. 7,17
参考文献
Poggi; Guastalla
Gazzetta Chimica Italiana, 1931 , vol. 61, p. 405,414, 428
参考文献
Criegee; Schnorrenberg; Becke
Justus Liebigs Annalen der Chemie, 1949 , vol. 565, p. 7,17
反应条件
nitric acid in octyl-iso-butyl; acetic acid
T=30 - 40°C; 2 h; Product distribution / selectivity;
参考文献
DEGUSSA INITIATORS GMBH and CO. KG
Patent: WO2004/76405 A1, 2004 ;
Location in patent: Page/Page column 8; 9 ;
