2,2’-二硫(六甲基二硅氮烷)合成路线 （共 8 条）
反应条件
bis(trimethylsilyl)-sulfide T=80 - 100°C;
参考文献
Mizhiritskii, M. D.; Reikhsfel'd, V. O.
J. Gen. Chem. USSR (Engl. Transl.), 1986 , vol. 56, # 7 p. 1547 - 1558,1373 - 1382
反应条件
SCl2 in diethyl ether -80 deg C, 1 h, -> -55 deg C, 2.5 h;
参考文献
Zibarev, A. V.; Gurin, G. G.; Yakobson, G. G.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1985 , vol. 34, p. 2571 - 2576
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1985 , # 12 p. 2774 - 2780
反应条件
in dichloromethane 24 h; Ambient temperature;
参考文献
Blaschette, Armand; Naeveke, Martina; Jones, Peter G.
Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1991 , vol. 46, # 1 p. 5 - 14
反应条件
disulfur dichloride; sulfur; n-butyllithium in carbon disulfide; diethyl ether 1.) 0 deg C, 2.) r.t., overnight; Title compound not separated from byproducts;
参考文献
Siivari, Jari; Maaninen, Arto; Haapaniemi, Esa; Laitinen, Risto S.; Chivers, Tristram
Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1995 , vol. 50, # 11 p. 1575 - 1582
反应条件
in carbon disulfide Ar; S-compd. soln. addn. dropwise to Se-compd. soln. at -78°C, mixt. allowing to warm slowly to room temp. (stirring, 12 h); elem. anal., (77)Se-NMR;
参考文献
Phosphorus, Sulfur and Silicon and Related Elements, , vol. 124, p. 457 - 460
反应条件
in carbon disulfide Ar; S-compds. soln. addn. dropwise to Se-compd. soln. at -78°C; elem. anal., (77)Se-NMR;
参考文献
Phosphorus, Sulfur and Silicon and Related Elements, , vol. 124, p. 457 - 460
反应条件
in dichloromethane
byproducts: Me3SiCl, SO2; Ar-atmosphere; equimolar amts.; dropwise addn. of mixt. of SCl2 and SO2Cl2 to amide at -78°C, stirring overnight with warming to room temp.; filtration, evapn., recrystn. (PhMe);
参考文献
Maaninen, Arto; Laitinen, Risto S.; Chivers, Tristram; Pakkanen, Tapani A.
Inorganic Chemistry, 1999 , vol. 38, p. 3450 - 3454
反应条件
in dichloromethane
byproducts: Me3SiCl; N2-atmosphere; dropwise addn. of mixt. of 1 equiv. SCl2 and 1 equiv. S2Cl2 to 1 equiv. Si-compd. at -78°C, slow warming to room temp., stirring for 12 h; filtration, evapn., sublimation (room temp., < 10 Pa), recrystn. (Et2O);
参考文献
Maaninen, Arto; Siivari, Jari; Suontamo, Reijo J.; Konu, Jari; Laitinen, Risto S.; Chivers, Tristram
Inorganic Chemistry, 1997 , vol. 36, # 10 p. 2170 - 2177
