反式-2-己烯醛二甲基乙缩醛合成路线 （共 8 条）
反应条件
lithium boron tetrafluoride in methanol T=50°C; 3 h;
参考文献
Hamada, Nao; Kazahaya, Kiyoshi; Shimizu, Hisashi; Sato, Tsuneo
Synlett, 2004 , # 6 p. 1074 - 1076
反应条件
1-(n-butyl)-3-methylimidazolium tetrachlorogallate T=20°C; 0.5 h;
参考文献
Yong, Jin Kim; Varma, Rajender S.
Tetrahedron Letters, 2005 , vol. 46, # 43 p. 7447 - 7449
反应条件
triethylamine in tetrahydrofuran T=20°C; oxidative elimination; 5 h; Title compound not separated from byproducts.;
参考文献
Journal of Organic Chemistry, , vol. 65, # 7 p. 2151 - 2162
反应条件
1.1: Br2 / CH2Cl2 / 25 - 30 °C 1.2: 83 percent / 0.05 h 2.1: 84 percent / K2CO3; N2H4*H2O / dimethylsulfoxide / 7 h / 70 °C 3.1: 30percent H2O2; Et3N / tetrahydrofuran / 5 h / 20 °C View Scheme
参考文献
Journal of Organic Chemistry, , vol. 65, # 7 p. 2151 - 2162
反应条件
1: 84 percent / K2CO3; N2H4*H2O / dimethylsulfoxide / 7 h / 70 °C 2: 30percent H2O2; Et3N / tetrahydrofuran / 5 h / 20 °C View Scheme
参考文献
Journal of Organic Chemistry, , vol. 65, # 7 p. 2151 - 2162
反应条件
tin(ll) chloride in dichloromethane 1 h; Ambient temperature;
参考文献
Ford, Kelley L.; Roskamp, Eric J.
Tetrahedron Letters, 1992 , vol. 33, # 9 p. 1135 - 1138
反应条件
boron trifluoride diethyl etherate in dichloromethane
T=-70°C;
参考文献
Nakamura, Eiichi; Shimada, Jun-ichi; Kuwajima, Isao
Journal of the Chemical Society, Chemical Communications, 1983 , # 9 p. 498 - 499
反应条件
1: 100 percent / BF3*Et2O / CH2Cl2 / -70 °C
2: 90 percent / KH / tetrahydrofuran / Ambient temperature
View Scheme
参考文献
Shimada,J.; Hashimoto,K.; Kim,B.H.
Journal of the American Chemical Society, 1984 , vol. 106, p. 1759
