(2E,4E)-2,4-癸二烯醇合成路线 （共 15 条）
反应条件
(MeO)2BF; dihydrogen peroxide; sec.-butyllithium in tetrahydrofuran effect of temperature and potassium t-butoxide; Product distribution;
参考文献
Helvetica Chimica Acta, , vol. 63, # 8 p. 2393 - 2403
反应条件
H2 activated rhodium-phosphinine complex in 1,4-dioxane T=60°C; 12 h;
参考文献
Reetz, Manfred T.; Guo, Hongchao
Synlett, 2006 , # 13 p. 2127 - 2129
反应条件
lithium boron tetrafluoride; tert.-butylnitrite; 2,2,6,6-tetramethyl-1-piperidinyloxy, free radical in dichloromethane; acetonitrile 3 h; Inert atmosphereReflux;
参考文献
Holan, Martin; Jahn, Ullrich
Organic Letters, 2014 , vol. 16, # 1 p. 58 - 61
反应条件
1: 87.5 percent / Br2, (Ph)3P / acetonitrile / Ambient temperature
2: 88 percent / tetrahydrofuran
3: 1.) n-butyllithium / 1.) THF, -78 deg C, 4 h, 2.) THF, overnight
4: 19 mg / n-butyllithium / diethyl ether / 0.03 h / -78 °C
View Scheme
参考文献
Ronald, Robert C.; Lansinger, Janet M.; Lillie, Thomas S.; Wheeler, Carl J.
Journal of Organic Chemistry, 1982 , vol. 47, # 13 p. 2541 - 2549
反应条件
1: 85 percent / Br2; PPh3 / acetonitrile / 0.17 h / 20 °C
2: 76 percent / NaH; BuLi / hexane; tetrahydrofuran / 0.5 h / 0 °C
View Scheme
参考文献
Mueller, Paul; Bolea, Christelle
Helvetica Chimica Acta, 2001 , vol. 84, # 5 p. 1093 - 1111
