(1S,2S,5S)-(-)-2-羟基-3-蒎酮合成路线 （共 16 条）
反应条件
1: n-butyllithium / tetrahydrofuran; hexane / 6 h / -78 °C / other temperature 2: hydroxylamine hydrochloride, AcONa*3H2O / ethanol / 19 h / Ambient temperature 3: 20percent aq. TiCl3, NH4OAc / H2O; dioxane / 6 h / 0 °C View Scheme
参考文献
Tetrahedron, , vol. 51, # 46 p. 12731 - 12744
反应条件
1: hydroxylamine hydrochloride, AcONa*3H2O / ethanol / 19 h / Ambient temperature 2: 20percent aq. TiCl3, NH4OAc / H2O; dioxane / 6 h / 0 °C View Scheme
参考文献
Tetrahedron, , vol. 51, # 46 p. 12731 - 12744
反应条件
1: 91 percent / n-butyllithium / tetrahydrofuran; hexane / 2 h / 0 °C 2: hydroxylamine hydrochloride, AcONa*3H2O / ethanol / 4 h / Ambient temperature 3: 20percent aq. TiCl3, NH4OAc / H2O; dioxane / 6 h / 0 °C View Scheme
参考文献
Tetrahedron, , vol. 51, # 46 p. 12731 - 12744
反应条件
lithium aluminium tetrahydride
参考文献
Carlson,R.G.; Pierce,J.K.
Journal of Organic Chemistry, 1971 , vol. 36, # 16 p. 2319 - 2324
反应条件
aluminum isopropoxide; isopropyl alcohol
参考文献
Katsuhara,J.
Bulletin of the Chemical Society of Japan, 1968 , vol. 41, # 11 p. 2700 - 2703
参考文献
Suga et al.
Bulletin of the Chemical Society of Japan, 1968 , vol. 41, p. 1180,1183
