1,6-二噁螺[2.5]辛烷合成路线 （共 12 条）
反应条件
3-chloro-benzenecarboperoxoic acid in dichloromethane T=0 - 20°C; 3 h;
参考文献
WO2008/96260 A1, ;
Page/Page column 62 ;
WO 2008/096260 A1
反应条件
sodium hydride in tetrahydrofuran; dimethyl sulfoxide; mineral oil T=0 - 20°C; 18 h; Inert atmosphere;
参考文献
US2012/46304 A1, ;
Page/Page column 178 ;
反应条件
tert-butoxide in dimethyl sulfoxide T=20°C; Inert atmosphere;
参考文献
WO2011/26917 A1, ;
Page/Page column 65 ;
WO 2011/026917 A1
反应条件
1: trimethyl-oxo-sulfonium iodide With sodium hydride in tetrahydrofuran; mineral oil 3 h; Inert atmosphereReflux; 2: tetrahydro-pyran-4-one in tetrahydrofuran; mineral oil 2 h; RefluxInert atmosphere;
参考文献
ChemMedChem, , vol. 5, # 1 p. 65 - 78
反应条件
1: alkali dichromate; aqueous H2SO4 2: methanol; diethyl ether View Scheme
参考文献
Chemische Berichte, , vol. 91, p. 1589,1594
反应条件
sodium hydride 1) THF, reflux, 1.5 h; 2) THF, 50-55 deg C, 3 h; Yield given. Multistep reaction;
参考文献
Phosphorus and Sulfur and the Related Elements, , vol. 19, p. 113 - 130
反应条件
methanol; diethyl ether
参考文献
Chemische Berichte, , vol. 91, p. 1589,1594
参考文献
Chemische Berichte, , vol. 91, p. 1589,1594
参考文献
Olsen; Bredoch
Chemische Berichte, 1958 , vol. 91, p. 1589,1594
参考文献
Olsen; Bredoch
Chemische Berichte, 1958 , vol. 91, p. 1589,1594
