1: Diazotization.Behandlung der Diazoniumsulfatloesung mit Jodwasserstoffsaeure 2: bromine / 200 °C / man destilliert das Produkt im Dampf von konz. Bromwasserstoffsaeure 3: man erhitzt das Nitril mit rauchender Salzsaeure auf 125grad View Scheme
1: acetone With potassium tert-butylate in dimethyl sulfoxide 0.166667 h; Inert atmosphere; 2: 2-(2-iodophenyl)acetic acid in dimethyl sulfoxide 2 h; Inert atmosphereIrradiation; 3: With ammonium nitrate; nitric acid in water
1: 3,3-dimethyl-butan-2-one With potassium tert-butylate in dimethyl sulfoxide 0.166667 h; Inert atmosphere; 2: 2-(2-iodophenyl)acetic acid in dimethyl sulfoxide 1 h; Inert atmosphereIrradiation; 3: With ammonium nitrate; nitric acid in water
1: cyclohexanone With potassium tert-butylate in dimethyl sulfoxide 0.166667 h; Inert atmosphere; 2: 2-(2-iodophenyl)acetic acid in dimethyl sulfoxide 2 h; Inert atmosphereIrradiation; 3: With ammonium nitrate; nitric acid in water
1: adamantan-1-yl-ethan-1-one With potassium tert-butylate in dimethyl sulfoxide 0.166667 h; Inert atmosphere; 2: 2-(2-iodophenyl)acetic acid in dimethyl sulfoxide 1 h; Inert atmosphereIrradiation; 3: With ammonium nitrate; nitric acid in water