3,4-dihydroxy-1-tert-butylbenzene in toluene T=170°C; 9.5 h;

1: 97.6 percent / H2 / 10percent Pd/C / toluene / 14 h / 60 - 70 °C / 3102.9 Torr 2: 55.9 percent / 192 h / Ambient temperature 3: diethyl ether / 24 h / Ambient temperature 4: 95 percent / 1 N HCl / CHCl3 View Scheme

1: 97.6 percent / H2 / 10percent Pd/C / toluene / 14 h / 60 - 70 °C / 3102.9 Torr 2: 55.9 percent / 192 h / Ambient temperature 3: 64 percent / diethyl ether / 24 h / Ambient temperature 4: 98 percent / 1 N HCl / CHCl3 5: 1.) CDI, 2.) Et3N / 1.) THF, RT, 2 h, 2.) THF, RT 6: KOH, HONH2*HCl / methanol / Ambient temperature View Scheme

1: 97.6 percent / H2 / 10percent Pd/C / toluene / 14 h / 60 - 70 °C / 3102.9 Torr 2: 55.9 percent / 192 h / Ambient temperature 3: 64 percent / diethyl ether / 24 h / Ambient temperature 4: 98 percent / 1 N HCl / CHCl3 View Scheme

暂无反应条件数据

暂无反应条件数据