Schwartz's reagent; water-d2 in toluene
T=40°C; 4 h; variation of time, amount of reagent, further olefins, deuterium labelling experiments; Product distributionMechanism;
参考文献
Annby, Ulf; Alvhaell, Joergen; Gronowitz, Salo; Hallberg, Anders
Journal of Organometallic Chemistry, 1989 , vol. 377, p. 75 - 84
copper(I) bromide dimethylsulfide complex; ethylmagnesium bromide; water in tetrahydrofuran
T=-30 - 20°C; 20 h; short and quick temperature rise, 2-3h reaction time; Product distributionMechanism;
参考文献
Sahlberg, Christer; Claesson, Alf
Journal of Organic Chemistry, 1984 , vol. 49, # 22 p. 4120 - 4122
ammonia; sodium in tetrahydrofuran
2 h; Heatingdifferent NH3/THF/substrate ratios; also with addition of methanol as quenching agent; also with addition of 2-methyl-2-propanol; Product distribution;
参考文献
Doolittle, Robert E.; Patrick, Delrea G.; Heath, Robert H.
Journal of Organic Chemistry, 1993 , vol. 58, # 19 p. 5063 - 5066