1-硝基-4-苯基乙炔苯合成路线 （共 107 条）
反应条件
dichloro bis(acetonitrile) palladium(II); nonafluoro-n-butanesulfonyl fluoride; caesium carbonate; 2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1’-biphenyl in acetonitrile
T=60°C; Sonogashira Cross-Coupling; 5 h; Inert atmosphere;
参考文献
Ikawa, Takashi; Saito, Kozumo; Akai, Shuji
Synlett, 2012 , vol. 23, # 15 p. 2241 - 2246
反应条件
[Pd((.eta.5-C5H5)Fe[(.eta.5-C5H3)C(Me)=N(C6H4-4-Me)])(.mu.-Cl)]2; potassium carbonate; 2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1’-biphenyl in anhydrous xylene; water
T=120°C; 3 h;
参考文献
Li, Xi'Ang; Yang, Fan; Wu, Yangjie
Journal of Organic Chemistry, 2013 , vol. 78, # 9 p. 4543 - 4550
反应条件
{(Pd{Fe(.eta.5-C5H5)(.eta.5-C5H3C(CH3)=NC6H4CH3-4)}(.mu.-Cl))2}; potassium carbonate; 2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1’-biphenyl in acetonitrile
T=110°C; 16 h; Inert atmosphere;
参考文献
Hu, Hao; Yang, Fan; Wu, Yangjie
Journal of Organic Chemistry, 2013 , vol. 78, # 20 p. 10506 - 10511
反应条件
1: 4-nitro-aniline With tert.-butylnitrite; boron trifluoride diethyl etherate in tetrahydrofuran
T=-15 - 20°C; Inert atmosphere;
2: phenylacetylene With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; tetra-(n-butyl)ammonium iodide; diethylamine in acetonitrile
T=20°C; Sonogashira coupling; 2 h;
参考文献
Fabrizi, Giancarlo; Goggiamani, Antonella; Sferrazza, Alessio; Cacchi, Sandro
Angewandte Chemie - International Edition, 2010 , vol. 49, # 24 p. 4067 - 4070
反应条件
caesium carbonate; bis(dibenzylideneacetone)-palladium(0) in methanol
T=20°C; Suzuki-Miyaura cross-coupling reaction; 12 h; Under air;
参考文献
Tang, Jian-Sheng; Tian, Mi; Sheng, Wen-Bing; Guo, Can-Cheng
Synthesis, 2012 , vol. 44, # 4 p. 541 - 546
反应条件
caesium carbonate; bis(dibenzylideneacetone)-palladium(0) in methanol
T=20°C; Suzuki-Miyaura cross-coupling reaction; 12 h; Under air;
参考文献
Tang, Jian-Sheng; Tian, Mi; Sheng, Wen-Bing; Guo, Can-Cheng
Synthesis, 2012 , vol. 44, # 4 p. 541 - 546
反应条件
caesium carbonate; bis(dibenzylideneacetone)-palladium(0) in methanol
T=20°C; Suzuki-Miyaura cross-coupling reaction; 36 h; Under air;
参考文献
Tang, Jian-Sheng; Tian, Mi; Sheng, Wen-Bing; Guo, Can-Cheng
Synthesis, 2012 , vol. 44, # 4 p. 541 - 546
反应条件
(Ph3P)2Pd(Ph)(I) in N,N,N',N',N'',N''-hexamethylphosphoric triamide
T=20°C; 0.333333 h; solvent effect; influences of additivities (Bu4NI, LiBr, LiCl); further catalysts; Product distributionMechanism;
参考文献
Bumagin, N. A.; Kalinovskii, I. O.; Ponomarev, A. B.; Beletskaya, I. P.
Doklady Chemistry, 1982 , vol. 265, p. 262 - 266
Dokl. Akad. Nauk SSSR Ser. Khim., 1982 , vol. 265, # 5 p. 1138 - 1143
反应条件
1: 1-chloro-4-nitro-benzene With diphenylphosphinoethane functionalized polystyrene resin-supported Pd(0) complex in N,N-dimethyl-formamide
T=20°C; Stille Cross Coupling; 0.25 h;
2: 1-tributylstannyl-2-phenylacetylene in N,N-dimethyl-formamide
T=120°C; Stille Cross Coupling; 13 h;
参考文献
Bahari, Siavash; Mohammadi-Aghdam, Babak; Molaei, Rahim; Gharibi, Zakiyeh
Canadian Journal of Chemistry, 2012 , vol. 90, # 9 p. 784 - 789
反应条件
2Na(1+)*CuC6H4(NCHC6H3OO3S)2(2-)=CuC6H4(NCHC6H3ONaO3S)2; tetrabutylammomium bromide; sodium hydroxide in water
T=100°C; 24 h; Sealed tube;
参考文献
Yu, Lintao; Jiang, Xiaofei; Wang, Lixia; Li, Zhengkai; Wu, Di; Zhou, Xiangge
European Journal of Organic Chemistry, 2010 , # 29 p. 5560 - 5562
