199620-14-9合成路线 （共 107 条）
反应条件
in [3.3.1]nonane
boiling;;
参考文献
Gmelin Handbook: Cr: Org.Verb., 1.6.1.2.1.3, page 200 - 211
反应条件
in [3.3.1]nonane
boiling;;
参考文献
Gmelin Handbook: Cr: Org.Verb., 1.6.1.2.1.3, page 200 - 211
反应条件
in benzene-d6
byproducts: H2; Irradiation (UV/VIS); (N2); UV irradn. of a soln. of boron compd. and Cr complex in C6D6 at 8°C in vac. for 1 h or irradn. for 5 min, then standing at room temp. for 1 d in the dark; not isolated, detected by NMR;
参考文献
Kawano, Yasuro; Uruichi, Mikio; Shimoi, Mamoru; Taki, Seitaro; Kawaguchi, Takayuki; Kakizawa, Taeko; Ogino, Hiroshi
Journal of the American Chemical Society, 2009 , vol. 131, # 41 p. 14946 - 14957
反应条件
(CH3)3NO*2H2O in acetonitrile
Cr(CO)6 and Me3NO*2H2O are stirred in MeCN (under Ar) for 20 min, addn. of Se-compd., boiling for 20 min; filtn., recrystn. from pentane/toluene, elem. anal.;
参考文献
Fedin, V. P.; Mironov, Yu. V.; Virovets, A. V.; Podberezskaya, N. V.; Fedorov, V. Ye.
Polyhedron, 1992 , vol. 11, p. 1959 - 1964
反应条件
(CH3)3NO*2H2O in acetonitrile
reaction of starting materials in MeCN (under Ar);
参考文献
Fedin, V. P.; Mironov, Yu. V.; Virovets, A. V.; Podberezskaya, N. V.; Fedorov, V. Ye.
Polyhedron, 1992 , vol. 11, p. 1959 - 1964
反应条件
trifluoroacetic anhydride
参考文献
Cook, Darren J.; Hill, Anthony F.
Organometallics, 1997 , vol. 16, # 26 p. 5616 - 5617
反应条件
in toluene
byproducts: Hg; to soln. of Cr(CO)6 in toluene was added soln. of Hg-complex, mixt. wasrefluxed for 6 h under N2; filtered, vol. was reduced;
参考文献
Lancashire, Robert; Smith, Thomas D.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 845 - 846
反应条件
in benzene-d6
byproducts: H2; Irradiation (UV/VIS); (N2); UV irradn. of a soln. of boron compd. and Cr complex in C6D6 at 8°C for 1 h; not isolated, detected by NMR;
参考文献
Kawano, Yasuro; Uruichi, Mikio; Shimoi, Mamoru; Taki, Seitaro; Kawaguchi, Takayuki; Kakizawa, Taeko; Ogino, Hiroshi
Journal of the American Chemical Society, 2009 , vol. 131, # 41 p. 14946 - 14957
反应条件
in tetrahydrofuran; diethylene glycol dimethyl ether
other Radiation; heating of diglyme and thf soln. of Cr(CO)6 and excess of piperidine for40 min in microwave oven; cooling, pptn., filtration, washing with hexane, drying in air;
参考文献
Ardon, Michael; Hogarth, Graeme; Oscroft, Daniel T.W.
Journal of Organometallic Chemistry, 2004 , vol. 689, # 15 p. 2429 - 2435
反应条件
in diethyl ether; hexane
Irradiation (UV/VIS); (N2 or Ar); Cr(CO)6 in ether irradiated, a soln. of carbene in hexane added at 0°C; evapd. (vac.), Cr(CO)6 sublimed off (vac., 30°C), extd. (ambient temp., hexane), evapd. (ambient temp., vac.), mixed with hexane, chromd.(hexane/ether), evapd.; elem. anal.;
参考文献
Herrmann, Wolfgang A.; Oefele, Karl; Preysing, Denise V.; Herdtweck, Eberhardt
Journal of Organometallic Chemistry, 2003 , vol. 684, # 1-2 p. 235 - 248
