199620-14-9合成路线 （共 107 条）
反应条件
in n-heptane
by reacting Cr(CO)6 with NHCH10 at reflux temp. in heptane; IR spectra (CH2Cl2);
参考文献
Bergstrom, Christina L.; Luck, Rudy L.
Inorganica Chimica Acta, 2001 , vol. 318, # 1-2 p. 77 - 83
反应条件
in benzene-d6
byproducts: H2; Irradiation (UV/VIS); (N2); UV irradn. of a soln. of boron compd. and Cr complex in C6D6 at 8°C for 1 h; not isolated, detected by NMR;
参考文献
Kawano, Yasuro; Uruichi, Mikio; Shimoi, Mamoru; Taki, Seitaro; Kawaguchi, Takayuki; Kakizawa, Taeko; Ogino, Hiroshi
Journal of the American Chemical Society, 2009 , vol. 131, # 41 p. 14946 - 14957
参考文献
Gmelin Handbook: Cr: Org.Verb., 1.1.2.1.5.2, page 66 - 70
反应条件
THF (catalyst) in tetrahydrofuran; anhydrous butyl ether
under N2, educts heated under reflux in n-Bu2O-THF for 21 h in the dark; cooled soln. filtered through Kieselguhr, evapd. in vac., solid dissolved in acetone, filtered, pptd. by addn. of light petroleum, recrystd. from acetone/light petroleum; elem. anal.;
参考文献
Mahaffy, Christopher A. L.
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1984 , vol. 14, p. 679 - 688
反应条件
THF in tetrahydrofuran
byproducts: CO; Irradiation (UV/VIS); Cr(CO)6 irradn. in THF; soln. warmed up to 50°C and -50°C BuBN(tBu)/THF soln. dropped into it; solvent and not converted Cr(CO)6 vac. evapd. at 40°C; dissolved in warm hexane; crystd. in cold; elem. anal.;
参考文献
Delpy, Klaus; Schmitz, Dieter; Paetzold, Peter
Chemische Berichte, 1983 , vol. 116, # 8 p. 2994 - 2999
反应条件
in diethylene glycol
参考文献
Magee et al.
Journal of the American Chemical Society, 1961 , vol. 83, p. 3200
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Gmelin Handbook: Cr: Org.Verb., 1.1.2.1.3, page 33 - 41
Full Text Show Details
Matthews, C. N.
Patent: GB946674 , 1964 ;
反应条件
4-(N,N-dimethlyamino)pyridine; palladium diacetate; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene in 1,4-dioxane
T=90°C; 0.5 h; Microwave irradiation;
参考文献
Baburajan, Poongavanam; Elango, Kuppanagounder P.
Tetrahedron Letters, 2014 , vol. 55, # 5 p. 1006 - 1010
