1,2-二(二苯基膦基)乙烷二氯化钯(II)合成路线 （共 27 条）
反应条件
hydrogenchloride in ethanol; water 8 h; Reflux;
参考文献
Comptes Rendus Chimie, , vol. 16, # 2 p. 159 - 175
反应条件
1,2-bis-(diphenylphosphino)ethane in benzene absence of oxygen; addn. of slight excess of diphosphine to Pd-complex (pptn.), stirring for 1 h; filtration; elem. anal.;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 1971 - 1976
反应条件
sodium chloride in water; acetonitrile Pd-compound in CH3CN was treated with aq. NaCl;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 67, # 6 p. 1746 - 1748
反应条件
hydrogenchloride in chloroform 298 K; soln. concd., crystals deposited;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 623 - 627
反应条件
in dimethyl sulfoxide prepn. according to: A. Westland, J. Chem. Soc., (1965) 3060; ligand is mixed with PdCl2 in DMSO and heated at 100°C untill a clear soln. is obtained; cooling down, filtn., washing with pentane;
参考文献
Inorganica Chimica Acta, , vol. 222, p. 381 - 385
反应条件
in tetrahydrofuran; ethanol stirring for 2 h; evapn., washing with H2O, drying at 80°C for 12 h;
参考文献
Inorganic Chemistry, , vol. 30, p. 125 - 130
反应条件
in dichloromethane under N2, addn. of complex in CH2Cl2 to soln. of ligand in CH2Cl2, stirred for 25°C for 2 h, white pptn.; evapd. under reduced press., addn. of toluene, heated under reflux for 4 h, yellow pptn., filtered, dried in vac.;
参考文献
Polyhedron, , vol. 12, p. 721 - 730
反应条件
in dimethyl sulfoxide room temp., 30 min; monitored by (1)H NMR;
参考文献
Polyhedron, , vol. 40, # 1 p. 168 - 174
反应条件
NaBF4 in dichloromethane byproducts: [HC(N(Et)CH2)2]BF4; N2-atmosphere; W:Pd molar ratio = 2:1, refluxing for 2 h; not sepd., NMR-spectroscopy;
参考文献
Organometallics, , vol. 18, # 11 p. 2145 - 2154
反应条件
NaBF4 in dichloromethane byproducts: [HC(N(CH2C6H5)CH2)2]BF4; N2-atmosphere; W:Pt molar ratio = 2:1, refluxing for 2 h; not sepd., NMR-spectroscopy;
参考文献
Organometallics, , vol. 18, # 11 p. 2145 - 2154
