2-溴-9,10-二苯基蒽合成路线 （共 11 条）
反应条件
sodium hypophosphite; potassium iodide in acetic acid 3 h; Heating / reflux;
参考文献
IDEMITSU KOSAN CO., LTD.
Patent: EP1734038 A1, 2006 ;
Location in patent: Page/Page column 42; 46 ;
反应条件
isopentyl nitrite in toluene T=80 - 100°C; 3 h;
参考文献
CANON KABUSHIKI KAISHA; KAMATANI, Jun; YAMADA, Naoki; KISHINO, Kengo; SAITOH, Akihito
Patent: WO2011/152477 A1, 2011 ;
Location in patent: Page/Page column 36-37 ;
反应条件
stannous chloride in tetrahydrofuran; acetic acid; acetone
反应条件
NaH2PO2; acetic acid; potassium iodide 6 h; Reflux;
参考文献
US2011/295017 A1, ;
Page/Page column 21 ;
反应条件
1: toluene; diethyl ether; anhydrous butyl ether / 6 h / -20 °C 2: potassium iodide; acetic acid; NaH2PO2 / 6 h / Reflux View Scheme
反应条件
1.1: copper(ll) bromide; tert.-butylnitrite / acetonitrile / 6 h / 65 °C 1.2: 3 h 2.1: tetrahydrofuran / 12 h / 20 °C / Inert atmosphere 3.1: potassium iodide; acetic acid; NaH2PO2 / 2 h / 120 °C 3.2: 1 h / 120 °C View Scheme
反应条件
1.1: tetrahydrofuran / 12 h / 20 °C / Inert atmosphere 2.1: potassium iodide; acetic acid; NaH2PO2 / 2 h / 120 °C 2.2: 1 h / 120 °C View Scheme
参考文献
Journal of the Chemical Society, , p. 3087
反应条件
1: With n-butyllithium in tetrahydrofuran; hexane
T=-78°C; 1 h;
2: With boric acid trimethyl ester in tetrahydrofuran; hexane
T=-78 - 20°C; 3 h;
3: With hydrogenchloride in tetrahydrofuran; hexane; water
1 h;
参考文献
IDEMITSU KOSAN CO., LTD.
Patent: EP1734038 A1, 2006 ;
Location in patent: Page/Page column 43; 46 ;
反应条件
1: 2-bromo-9,10-diphenylanthracene With n-butyllithium in tetrahydrofuran
T=-78°C; 1 h;
2: boric acid trimethyl ester in tetrahydrofuran
T=20°C; 4 h;
3: With hydrogenchloride in tetrahydrofuran; water
参考文献
Samsung Mobile Display Co., Ltd.
Patent: EP2292604 A2, 2011 ;
Location in patent: Page/Page column 22 ;
